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Nanofabrication of synthetic nanoporous geomaterials: from nanoscale-resolution 3D imaging to nano-3D-printed digital (shale) rock

Journal Article · · Scientific Reports

Abstract

Advances in imaging have made it possible to view nanometer and sub-nanometer structures that are either synthesized or that occur naturally. It is believed that fluid dynamic and thermodynamic behavior differ significantly at these scales from the bulk. From a materials perspective, it is important to be able to create complex structures at the nanometer scale, reproducibly, so that the fluid behavior may be studied. New advances in nanoscale-resolution 3D-printing offer opportunities to achieve this goal. In particular, additive manufacturing with two-photon polymerization allows creation of intricate structures. Using this technology, a creation of the first nano-3D-printed digital (shale) rock is reported. In this paper, focused ion beam-scanning electron microscopy (FIB-SEM) nano-tomography image dataset was used to reconstruct a high-resolution digital rock 3D model of a Marcellus Shale rock sample. Porosity of this 3D model has been characterized and its connected/effective pore system has been extracted and nano-3D-printed. The workflow of creating this novel nano-3D-printed digital rock 3D model is described in this paper.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0019285
OSTI ID:
1734817
Alternate ID(s):
OSTI ID: 1817074
Journal Information:
Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 10; ISSN 2045-2322
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United Kingdom
Language:
English

References (39)

Fabrication and Characterization of Magnetic Microrobots for Three‐Dimensional Cell Culture and Targeted Transportation journal July 2013
3D Plate-Lattices: An Emerging Class of Low-Density Metamaterial Exhibiting Optimal Isotropic Stiffness journal September 2018
Effect of confinement on the bubble points of hydrocarbons in nanoporous media journal January 2016
Effect of the presence of organic matter on bubble points of oils in shales journal January 2017
Three-dimensional optical laser lithography beyond the diffraction limit: 3D optical lithography off limits journal March 2012
Hybrid Helical Magnetic Microrobots Obtained by 3D Template-Assisted Electrodeposition journal December 2013
Two‐Photon Vertical‐Flow Lithography for Microtube Synthesis journal June 2019
3D-Printed Stationary Phases with Ordered Morphology: State of the Art and Future Development in Liquid Chromatography journal December 2018
Spatial characterization of heterogeneous nanopore surfaces from XCT scans of Niobrara shale journal July 2019
A GPU-accelerated package for simulation of flow in nanoporous source rocks with many-body dissipative particle dynamics journal February 2020
A novel upscaling procedure for characterising heterogeneous shale porosity from nanometer-to millimetre-scale in 3D journal August 2019
Pore system characterization of organic-rich shales using nanoscale-resolution 3D imaging journal December 2019
Highly porous microlattices as ultrathin and efficient impact absorbers journal October 2018
Correlative core- to pore-scale imaging of shales journal January 2020
Industrial applications of digital rock technology journal August 2017
Macro- and micro-compression testing of shales journal August 2020
Experimental and Molecular Modeling Study of Bubble Points of Hydrocarbon Mixtures in Nanoporous Media journal February 2017
Slip Flow through Colloidal Crystals of Varying Particle Diameter journal December 2012
Simultaneous additive and subtractive three-dimensional nanofabrication using integrated two-photon polymerization and multiphoton ablation journal April 2012
Fabrication of arbitrary three-dimensional suspended hollow microstructures in transparent fused silica glass journal March 2019
Re-epithelialization and immune cell behaviour in an ex vivo human skin model journal January 2020
Confinement Effect on Porosity and Permeability of Shales journal January 2020
Study of Gas Flow Characteristics in Tight Porous Media with a Microscale Lattice Boltzmann Model journal September 2016
Integrative optofluidic microcavity with tubular channels and coupled waveguides via two-photon polymerization journal January 2016
Wall-less liquid pathways formed with three-dimensional microring arrays journal September 2012
Many-body dissipative particle dynamics modeling of fluid flow in fine-grained nanoporous shales journal May 2017
Microfluidic swap structure to enhance on-chip liquid mixing conference October 2017
Fabrication of microneedles precisely imitating mosquito's proboscis by nanoscale tree dimensional laser lithography and its characterization
  • Suzuki, M.; Sawa, T.; Terada, Y.
  • TRANSDUCERS 2015 - 2015 18th International Solid-State Sensors, Actuators and Microsystems Conference, 2015 Transducers - 2015 18th International Conference on Solid-State Sensors, Actuators and Microsystems (TRANSDUCERS) https://doi.org/10.1109/TRANSDUCERS.2015.7180876
conference June 2015
Using Resin-Based 3D Printing to Build Geometrically Accurate Proxies of Porous Sedimentary Rocks: S. Ishutov et al. Groundwater XX, no. X: XX-XX journal September 2017
Three-dimensional printing for geoscience: Fundamental research, education, and applications for the petroleum industry journal January 2018
Three-dimensional-printed gas dynamic virtual nozzles for x-ray laser sample delivery journal January 2016
Three-dimensional pore networks and transport properties of a shale gas formation determined from focused ion beam serial imaging journal January 2012
Advances in 3D focused ion beam tomography journal April 2014
High Resolution CT And Pore-Network Models To Assess Petrophysical Properties Of Homogeneous And Heterogeneous Carbonates conference April 2013
Pore Network Investigation in Marcellus Shale Rock Matrix conference November 2015
A Workflow for Multi-Scale Modeling and Simulation of Transport Phenomena in Woodford Shale Rock Matrix conference August 2015
Modeling and Simulation of Transport Phenomena in Organic-Rich Marcellus Shale Rock Matrix conference October 2017
Correlative XRM and FIB-SEM for (Non)Organic Pore Network Modeling in Woodford Shale Rock Matrix conference December 2015
Correlative Multiscale Imaging of Mancos Shale conference March 2019

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