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An interval of high salinity in ancient Gale crater lake on Mars

Journal Article · · Nature Geoscience
 [1];  [2];  [3];  [4];  [1];  [1];  [1];  [1];  [5];  [6];  [7];  [8];  [1];  [9];  [9];  [10];  [11];  [12];  [2]
  1. California Institute of Technology (CalTech), Pasadena, CA (United States)
  2. California Institute of Technology (CalTech), Pasadena, CA (United States). Jet Propulsion Lab. (JPL)
  3. Univ. of Lyon (France)
  4. Indiana Univ., Bloomington, IN (United States)
  5. Texas A & M Univ., College Station, TX (United States)
  6. Space Science Inst., Boulder, CO (United States)
  7. Univ. of Tennessee, Knoxville, TN (United States)
  8. Univ. of New Brunswick, Fredericton NB (Canada)
  9. Arizona State Univ., Tempe, AZ (United States)
  10. Univ. Nantes (France); Univ. Angers (France)
  11. Dartmouth College, Hanover, NH (United States)
  12. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Precipitated minerals, including salts, are primary tracers of atmospheric conditions and water chemistry in lake basins. Ongoing in situ exploration by the Curiosity rover of Hesperian (around 3.3–3.7 Gyr old) sedimentary rocks within Gale crater on Mars has revealed clay-bearing fluvio-lacustrine deposits with sporadic occurrences of sulfate minerals, primarily as late-stage diagenetic veins and concretions. In this work, we report bulk enrichments, disseminated in the bedrock, of 30–50 wt% calcium sulfate intermittently over about 150 m of stratigraphy, and of 26–36 wt% hydrated magnesium sulfate within a thinner section of strata. We use geochemical analysis, primarily from the ChemCam laser-induced breakdown spectrometer, combined with results from other rover instruments, to characterize the enrichments and their lithology. The deposits are consistent with early diagenetic, pre-compaction salt precipitation from brines concentrated by evaporation, including magnesium sulfate-rich brines from extreme evaporative concentration. This saline interval represents a substantial hydrological perturbation of the lake basin, which may reflect variations in Mars’ obliquity and orbital parameters. Our findings support stepwise changes in Martian climate during the Hesperian, leading to more arid and sulfate-dominated environments as previously inferred from orbital observations.
Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
National Aeronautic and Space Administration (NASA); USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
89233218CNA000001
OSTI ID:
1734724
Report Number(s):
LA-UR--19-32327
Journal Information:
Nature Geoscience, Journal Name: Nature Geoscience Journal Issue: 11 Vol. 12; ISSN 1752-0908; ISSN 1752-0894
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

References (45)

Molecular and phenetic characterization of the bacterial assemblage of Hot Lake, WA, an environment with high concentrations of magnesium sulphate, and its relevance to Mars journal January 2014
Microbial Diversity in a Hypersaline Sulfate Lake: A Terrestrial Analog of Ancient Mars journal September 2017
Sequence of infilling events in Gale Crater, Mars: Results from morphology, stratigraphy, and mineralogy: SEDIMENTARY INFILLING IN GALE CRATER journal December 2013
Calcium sulfate veins characterized by ChemCam/Curiosity at Gale crater, Mars: CALCIUM SULFATE VEINS AT GALE CRATER journal September 2014
The stratigraphy and evolution of lower Mount Sharp from spectral, morphological, and thermophysical orbital data sets: Stratigraphy and Evolution of Mount Sharp journal September 2016
Characterization of LIBS emission lines for the identification of chlorides, carbonates, and sulfates in salt/basalt mixtures for the application to MSL ChemCam data: LIBS OF CL, C, S IN SALT-BASALT MIXTURES journal April 2017
Deconvolution of distinct lithology chemistry through oversampling with the Mars Science Laboratory Alpha Particle X-Ray Spectrometer: Deconvolution of distinct lithology chemistry with the MSL APXS journal February 2016
Mars Science Laboratory Mission and Science Investigation journal July 2012
The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Body Unit and Combined System Tests journal June 2012
The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Science Objectives and Mast Unit Description journal July 2012
Chemistry and mineralogy of outcrops at Meridiani Planum journal November 2005
Geochemical modeling of evaporation processes on Mars: Insight from the sedimentary record at Meridiani Planum journal November 2005
Chemical divides and evaporite assemblages on Mars journal January 2006
Hydration state of calcium sulfates in Gale crater, Mars: Identification of bassanite veins journal October 2016
Experimental stability of magnesium sulfate hydrates that may be present on Mars journal January 2007
Long term evolution and chaotic diffusion of the insolation quantities of Mars journal August 2004
Detection and discrimination of sulfate minerals using reflectance spectroscopy journal September 2006
Detection and identification of salts and frozen salt solutions combining laser-induced breakdown spectroscopy and multivariate analysis methods: A study for future martian exploration journal March 2013
Chemistry of diagenetic features analyzed by ChemCam at Pahrump Hills, Gale crater, Mars journal January 2017
Using ChemCam LIBS data to constrain grain size in rocks on Mars: Proof of concept and application to rocks at Yellowknife Bay and Pahrump Hills, Gale crater journal March 2019
Chemical alteration of fine-grained sedimentary rocks at Gale crater journal March 2019
An improvement to the volcano-scan algorithm for atmospheric correction of CRISM and OMEGA spectral data journal June 2009
Strategies for Mars remote Laser-Induced Breakdown Spectroscopy analysis of sulfur in geological samples journal January 2011
Extraction of compositional and hydration information of sulfates from laser-induced plasma spectra recorded under Mars atmospheric conditions — Implications for ChemCam investigations on Curiosity rover journal February 2012
Recalibration of the Mars Science Laboratory ChemCam instrument with an expanded geochemical database journal March 2017
Quantification of water content by laser induced breakdown spectroscopy on Mars journal April 2017
Biosedimentary and geochemical constraints on the precipitation of mineral crusts in shallow sulphate lakes journal April 2018
Molecular and phenetic characterization of the bacterial assemblage of Hot Lake, WA, an environment with high concentrations of magnesium sulphate, and its relevance to Mars journal January 2014
Paleoclimate of Mars as captured by the stratigraphic record in Gale Crater: STRATIGRAPHY OF GALE CRATER journal February 2010
Mars Science Laboratory Observations of Chloride Salts in Gale Crater, Mars journal October 2019
Magnetite authigenesis and the warming of early Mars journal August 2018
Encounters with an unearthly mudstone: Understanding the first mudstone found on Mars journal November 2016
Syndepositional precipitation of calcium sulfate in Gale Crater, Mars journal September 2018
Clay mineral diversity and abundance in sedimentary rocks of Gale crater, Mars journal June 2018
Global Mineralogical and Aqueous Mars History Derived from OMEGA/Mars Express Data journal April 2006
Elemental Geochemistry of Sedimentary Rocks at Yellowknife Bay, Gale Crater, Mars journal December 2013
Deposition, exhumation, and paleoclimate of an ancient lake deposit, Gale crater, Mars journal October 2015
Redox stratification of an ancient lake in Gale crater, Mars journal June 2017
Sulfate minerals and organic compounds on Mars journal January 2006
Desiccation cracks provide evidence of lake drying on Mars, Sutton Island member, Murray formation, Gale Crater journal April 2018
Studying of water consent in Mars’ gale crater: The first results of the DAN experiment on the NASA curiosity rover journal March 2014
Mineralogy of the Martian Surface journal May 2014
Numerically stable algorithm for discrete-ordinate-method radiative transfer in multiple scattering and emitting layered media journal January 1988
Gypsum, bassanite, and anhydrite at Gale crater, Mars journal July 2018
Transformations of Mg- and Ca-sulfate hydrates in Mars regolith journal October 2006

Cited By (2)

Mars Science Laboratory Observations of Chloride Salts in Gale Crater, Mars journal October 2019
Additional file 1 of Sulfur-cycling chemolithoautotrophic microbial community dominates a cold, anoxic, hypersaline Arctic spring dataset January 2023

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