skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Crystal Structure and Melting of Fe Shock Compressed to 273 GPa: In Situ X-Ray Diffraction

Journal Article · · Physical Review Letters

Despite extensive shock wave and static compression experiments and corresponding theoretical work, consensus on the crystal structure and the melt boundary of Fe at Earth’s core conditions is lacking. We present in situ x-ray diffraction measurements in laser-shock compressed Fe that establish the stability of the hexagonal-close-packed (hcp) structure along the Hugoniot through shock melting, which occurs between ~242 to ~247 GPa. Using previously reported hcp Fe Hugoniot temperatures, the melt temperature is estimated to be 5560(360) K at 242 GPa, consistent with several reported Fe melt curves. Extrapolation of this value suggests ~6400 K melt temperature at Earth’s inner core boundary pressure.

Research Organization:
Washington State Univ., Pullman, WA (United States). Inst. for Shock Physics
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA), Office of Defense Programs (DP); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
Grant/Contract Number:
NA0002007; AC02-06CH11357; NA0003957; NA0002442
OSTI ID:
1728707
Alternate ID(s):
OSTI ID: 1728710; OSTI ID: 1729906
Journal Information:
Physical Review Letters, Vol. 125, Issue 21; ISSN 0031-9007
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English

References (46)

Synchrotron X-ray Study of Iron at High Pressure and Temperature journal September 1995
Melting properties from ab initio free energy calculations: Iron at the Earth's inner-core boundary journal December 2018
Temperature of the inner-core boundary of the Earth: Melting of iron at high pressure from first-principles coexistence simulations journal February 2009
Melting curve of iron to 290 GPa determined in a resistance-heated diamond-anvil cell journal March 2019
En las condiciones del núcleo de la Tierra, ¿tiene el hierro una estructura hcp? journal January 1970
Solving Controversies on the Iron Phase Diagram Under High Pressure journal October 2018
Polymorphism of Iron at High Pressure journal March 1956
Thermodynamics of hexagonal-close-packed iron under Earth’s core conditions journal July 2001
The laser shock station in the dynamic compression sector. I journal May 2019
Laser interferometer for measuring high velocities of any reflecting surface journal November 1972
Melting of Iron under Earth’s Core Conditions from Diffusion Monte Carlo Free Energy Calculations journal August 2009
Physics of Iron at Earth's Core Conditions journal February 2000
Pure Iron Compressed and Heated to Extreme Conditions journal October 2007
Temperatures in the Earth's core from melting-point measurements of iron at high static pressures journal June 1993
In situ x-ray diffraction measurements of the c / a ratio in the high-pressure ε phase of shock-compressed polycrystalline iron journal April 2011
The Orthorhombic Structure of Iron: An in Situ Study at High-Temperature and High-Pressure journal October 1997
Shock temperatures and melting of iron at Earth core conditions journal June 1993
Stability of the body-centred-cubic phase of iron in the Earth's inner core journal August 2003
The electronic band structures of iron, sulfur, and oxygen at high pressures and the Earth's core journal January 1990
The effect of pressure on the volume and lattice parameters of ruthenium and iron journal August 1964
Hugoniot data for iron journal November 2000
Iron under Earth’s core conditions: Liquid-state thermodynamics and high-pressure melting curve from ab initio calculations journal April 2002
Phase Diagram of Iron by in Situ X-ray Diffraction: Implications for Earth's Core journal December 1995
The equation of state of iron to 450 GPa: Another high pressure solid phase? journal November 2001
Subnanosecond phase transition dynamics in laser-shocked iron journal June 2020
Melting of iron at the physical conditions of the Earth's core journal January 2004
In Situ X-Ray Study of Thermal Expansion and Phase Transition of Iron at Multimegabar Pressure journal February 2000
Theory of the iron phase diagram at Earth core conditions journal January 1990
Dynamic X-ray diffraction observation of shocked solid iron up to 170 GPa journal June 2016
Solid Iron Compressed Up to 560 GPa journal August 2013
Anisotropy of the inner core from differential travel times of the phases PKP and PKIKP journal March 1992
Shock wave study of the α ⇄ ε phase transition in iron journal November 1974
Elastic Anisotropy of Earth's Inner Core journal February 2008
Quenching of bcc-Fe from high to room temperature at high-pressure conditions: a molecular dynamics simulation journal September 2009
Shock Melting Curve of Iron: A Consensus on the Temperature at the Earth's Inner Core Boundary journal August 2020
High-pressure nanocrystalline structure of a shock-compressed single crystal of iron journal December 2008
Melting of Iron at Earth's Inner Core Boundary Based on Fast X-ray Diffraction journal April 2013
The Structure of Iron in Earth's Inner Core journal October 2010
Sound velocity, equation of state, temperature and melting of LiF single crystals under shock compression journal January 2015
Stabilization of body-centred cubic iron under inner-core conditions journal February 2017
Probing local and electronic structure in Warm Dense Matter: single pulse synchrotron x-ray absorption spectroscopy on shocked Fe journal June 2016
Phase transitions, Grüneisen parameter, and elasticity for shocked iron between 77 GPa and 400 GPa journal June 1986
Earth's Core and the Geodynamo journal June 2000
First-principles thermal equation of state and thermoelasticity of hcp Fe at high pressures journal March 2010
Two-dimensional detector software: From real detector to idealised image or two-theta scan journal January 1996
Thermal properties of iron at high pressures and temperatures journal April 1996