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Materials Data on Zr2(TiSi)3 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1725252· OSTI ID:1725252
Zr2(TiSi)3 crystallizes in the hexagonal P6_3/mcm space group. The structure is three-dimensional. Zr2+ is bonded to six equivalent Si4- atoms to form a mixture of corner, edge, and face-sharing ZrSi6 octahedra. The corner-sharing octahedral tilt angles are 40°. All Zr–Si bond lengths are 2.78 Å. Ti+2.67+ is bonded in a 5-coordinate geometry to five equivalent Si4- atoms. There are a spread of Ti–Si bond distances ranging from 2.57–2.89 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Zr2+ and five equivalent Ti+2.67+ atoms.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1725252
Report Number(s):
mp-1215754
Country of Publication:
United States
Language:
English

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