Highly Efficient and Stable Perovskite Solar Cells Enabled by Low‐Cost Industrial Organic Pigment Coating

He, Qingquan; Worku, Michael; Liu, He; Lochner, Eric; Robb, Alex J.; Lteif, Sandrine; Vellore Winfred, J. S. Raaj; Hanson, Kenneth; Schlenoff, Joseph B.; Kim, Bumjoon J.; Ma, Biwu

doi:10.1002/ange.202012095

Title: Highly Efficient and Stable Perovskite Solar Cells Enabled by Low‐Cost Industrial Organic Pigment Coating

Journal Article · Fri Nov 27 00:00:00 EST 2020 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.202012095· OSTI ID:1724438

He, Qingquan ^[1]; Worku, Michael ^[2]; Liu, He ^[1]; Lochner, Eric ^[3]; Robb, Alex J. ^[1]; Lteif, Sandrine ^[1]; Vellore Winfred, J. S. Raaj ^[1]; Hanson, Kenneth ^[1]; Schlenoff, Joseph B. ^[1]; Kim, Bumjoon J. ^[4];

^[5]

Department of Chemistry and Biochemistry Florida State University Tallahassee FL 32306 USA
Materials Science and Engineering Program Florida State University Tallahassee FL 32306 USA
Department of Physics Florida State University Tallahassee FL 32306 USA
Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology Daejeon 34141 Republic of Korea
Department of Chemistry and Biochemistry Florida State University Tallahassee FL 32306 USA, Materials Science and Engineering Program Florida State University Tallahassee FL 32306 USA

Abstract Surface passivation of perovskite solar cells (PSCs) using a low‐cost industrial organic pigment quinacridone (QA) is presented. The procedure involves solution processing a soluble derivative of QA, N , N ‐bis(tert‐butyloxycarbonyl)‐quinacridone (TBOC‐QA), followed by thermal annealing to convert TBOC‐QA into insoluble QA. With halide perovskite thin films coated by QA, PSCs based on methylammonium lead iodide (MAPbI ₃ ) showed significantly improved performance with remarkable stability. A PCE of 21.1 % was achieved, which is much higher than 18.9 % recorded for the unmodified devices. The QA coating with exceptional insolubility and hydrophobicity also led to greatly enhanced contact angle from 35.6° for the pristine MAPbI ₃ thin films to 77.2° for QA coated MAPbI ₃ thin films. The stability of QA passivated MAPbI ₃ perovskite thin films and PSCs were significantly enhanced, retaining about 90 % of the initial efficiencies after more than 1000 hours storage under ambient conditions.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1724438

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 133 Journal Issue: 5; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (52)

Imperfections and their passivation in halide perovskite solar cells Chen, Bo; Rudd, Peter N.; Yang, Shuang Chemical Society Reviews, Vol. 48, Issue 14 https://doi.org/10.1039/C8CS00853A	journal	January 2019
Oxidative Passivation of Metal Halide Perovskites Godding, Julian S. W.; Ramadan, Alexandra J.; Lin, Yen-Hung Joule, Vol. 3, Issue 11 https://doi.org/10.1016/j.joule.2019.08.006	journal	November 2019
Pi-Extended Diindole-Fused Azapentacenone: Synthesis, Characterization, and Photophysical and Lithium-Storage Properties Zhao, Jianfeng; Li, Renping; Ai, Wei Chemistry - An Asian Journal, Vol. 11, Issue 9 https://doi.org/10.1002/asia.201501366	journal	January 2016
Surface passivation of perovskite film for efficient solar cells Jiang, Qi; Zhao, Yang; Zhang, Xingwang Nature Photonics, Vol. 13, Issue 7 https://doi.org/10.1038/s41566-019-0398-2	journal	April 2019
NbF ₅ : A Novel α‐Phase Stabilizer for FA‐Based Perovskite Solar Cells with High Efficiency Yuan, Shihao; Qian, Fang; Yang, Shaomin Advanced Functional Materials, Vol. 29, Issue 47 https://doi.org/10.1002/adfm.201807850	journal	February 2019
Charge extraction via graded doping of hole transport layers gives highly luminescent and stable metal halide perovskite devices Abdi-Jalebi, Mojtaba; Ibrahim Dar, M.; Senanayak, Satyaprasad P. Science Advances, Vol. 5, Issue 2 https://doi.org/10.1126/sciadv.aav2012	journal	February 2019
Direct Electrochemical Capture and Release of Carbon Dioxide Using an Industrial Organic Pigment: Quinacridone Apaydin, Dogukan Hazar; Głowacki, Eric Daniel; Portenkirchner, Engelbert Angewandte Chemie International Edition, Vol. 53, Issue 26 https://doi.org/10.1002/anie.201403618	journal	May 2014
Dopant-free novel hole-transporting materials based on quinacridone dye for high-performance and humidity-stable mesoporous perovskite solar cells Pham, Hong Duc; Jain, Sagar M.; Li, Meng Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/C8TA11361K	journal	January 2019
Heavy Water Additive in Formamidinium: A Novel Approach to Enhance Perovskite Solar Cell Efficiency Solanki, Ankur; Tavakoli, Mohammad Mahdi; Xu, Qiang Advanced Materials, Vol. 32, Issue 23 https://doi.org/10.1002/adma.201907864	journal	April 2020
Constructive molecular configurations for surface-defect passivation of perovskite photovoltaics Wang, Rui; Xue, Jingjing; Wang, Kai-Li Science, Vol. 366, Issue 6472 https://doi.org/10.1126/science.aay9698	journal	December 2019
Promoting Thermodynamic and Kinetic Stabilities of FA-based Perovskite by an in Situ Bilayer Structure Xu, Alex Fan; Liu, Na; Xie, Fanlong Nano Letters, Vol. 20, Issue 5 https://doi.org/10.1021/acs.nanolett.0c00988	journal	April 2020
Modulation of Defects and Interfaces through Alkylammonium Interlayer for Efficient Inverted Perovskite Solar Cells Wu, Shengfan; Zhang, Jie; Li, Zhen Joule, Vol. 4, Issue 6 https://doi.org/10.1016/j.joule.2020.04.001	journal	June 2020
Toward Eco-friendly and Stable Perovskite Materials for Photovoltaics Ju, Ming-Gang; Chen, Min; Zhou, Yuanyuan Joule, Vol. 2, Issue 7 https://doi.org/10.1016/j.joule.2018.04.026	journal	July 2018
Intermolecular π–π Conjugation Self‐Assembly to Stabilize Surface Passivation of Highly Efficient Perovskite Solar Cells Li, Hongshi; Shi, Jiangjian; Deng, Jun Advanced Materials, Vol. 32, Issue 23 https://doi.org/10.1002/adma.201907396	journal	April 2020
Epindolidione-Based Conjugated Polymers: Synthesis, Electronic Structures, and Charge Transport Properties Yang, Chi-Yuan; Shi, Ke; Lei, Ting ACS Applied Materials & Interfaces, Vol. 8, Issue 6 https://doi.org/10.1021/acsami.5b07715	journal	September 2015
Fabrication of Efficient and Stable Perovskite Solar Cells in High‐Humidity Environment through Trace‐Doping of Large‐Sized Cations Liu, Xueping; He, Jiang; Wang, Pengfei ChemSusChem https://doi.org/10.1002/cssc.201900106	journal	April 2019
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Surface passivation of perovskite thin films by phosphonium halides for efficient and stable solar cells He, Qingquan; Worku, Michael; Xu, Liangjin Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/C9TA12597C	journal	January 2020
A dual function-enabled novel zwitterion to stabilize a Pb–I framework and passivate defects for highly efficient inverted planar perovskite solar cells Wang, Deng; Huang, Lei; Chen, Qiyin Chemical Communications, Vol. 56, Issue 51 https://doi.org/10.1039/D0CC02613A	journal	January 2020
Bifunctional Stabilization of All-Inorganic α-CsPbI ₃ Perovskite for 17% Efficiency Photovoltaics Wang, Yong; Zhang, Taiyang; Kan, Miao Journal of the American Chemical Society, Vol. 140, Issue 39 https://doi.org/10.1021/jacs.8b07927	journal	September 2018
Selective growth of layered perovskites for stable and efficient photovoltaics Cho, Kyung Taek; Grancini, Giulia; Lee, Yonghui Energy & Environmental Science, Vol. 11, Issue 4 https://doi.org/10.1039/C7EE03513F	journal	January 2018
Quinacridone-Based Molecular Donors for Solution Processed Bulk-Heterojunction Organic Solar Cells Chen, John Jun-An; Chen, Teresa L.; Kim, BongSoo ACS Applied Materials & Interfaces, Vol. 2, Issue 9, p. 2679-2686 https://doi.org/10.1021/am100523g	journal	August 2010
Defect and Contact Passivation for Perovskite Solar Cells Aydin, Erkan; Bastiani, Michele; Wolf, Stefaan Advanced Materials, Vol. 31, Issue 25 https://doi.org/10.1002/adma.201900428	journal	April 2019
CuGaO ₂ : A Promising Inorganic Hole-Transporting Material for Highly Efficient and Stable Perovskite Solar Cells Zhang, Hua; Wang, Huan; Chen, Wei Advanced Materials, Vol. 29, Issue 8 https://doi.org/10.1002/adma.201604984	journal	December 2016
Fully solution processed p-i-n organic solar cells with an industrial pigment – Quinacridone Chen, Teresa L.; Chen, John Jun-An; Catane, Luis Organic Electronics, Vol. 12, Issue 7 https://doi.org/10.1016/j.orgel.2011.03.039	journal	July 2011
Improving the stability and performance of perovskite solar cells via off-the-shelf post-device ligand treatment Zhang, Hong; Ren, Xingang; Chen, Xiwen Energy & Environmental Science, Vol. 11, Issue 8 https://doi.org/10.1039/C8EE00580J	journal	January 2018
Efficient and stable solution-processed planar perovskite solar cells via contact passivation Tan, Hairen; Jain, Ankit; Voznyy, Oleksandr Science, Vol. 355, Issue 6326 https://doi.org/10.1126/science.aai9081	journal	February 2017
Facile Formation of 2D–3D Heterojunctions on Perovskite Thin Film Surfaces for Efficient Solar Cells He, Qingquan; Worku, Michael; Xu, Liangjin ACS Applied Materials & Interfaces, Vol. 12, Issue 1 https://doi.org/10.1021/acsami.9b17851	journal	December 2019
Targeted Therapy for Interfacial Engineering Toward Stable and Efficient Perovskite Solar Cells Wang, Shuhui; Chen, Haiyang; Zhang, Jiandong Advanced Materials, Vol. 31, Issue 41 https://doi.org/10.1002/adma.201903691	journal	August 2019
Tailored Phase Conversion under Conjugated Polymer Enables Thermally Stable Perovskite Solar Cells with Efficiency Exceeding 21% Meng, Lei; Sun, Chenkai; Wang, Rui Journal of the American Chemical Society, Vol. 140, Issue 49 https://doi.org/10.1021/jacs.8b10520	journal	November 2018
Efficient and Stable Chemical Passivation on Perovskite Surface via Bidentate Anchoring Zhang, Hao; Wu, Yongzhen; Shen, Chao Advanced Energy Materials, Vol. 9, Issue 13 https://doi.org/10.1002/aenm.201803573	journal	February 2019
Adsorption, desorption, and film formation of quinacridone and its thermal cracking product indigo on clean and carbon-covered silicon dioxide surfaces Scherwitzl, Boris; Lassnig, Roman; Truger, Magdalena The Journal of Chemical Physics, Vol. 145, Issue 9 https://doi.org/10.1063/1.4961738	journal	September 2016
Synergistic Crystal and Interface Engineering for Efficient and Stable Perovskite Photovoltaics Tavakoli, Mohammad Mahdi; Saliba, Michael; Yadav, Pankaj Advanced Energy Materials, Vol. 9, Issue 1 https://doi.org/10.1002/aenm.201802646	journal	November 2018
Stabilizing halide perovskite surfaces for solar cell operation with wide-bandgap lead oxysalts Yang, Shuang; Chen, Shangshang; Mosconi, Edoardo Science, Vol. 365, Issue 6452 https://doi.org/10.1126/science.aax3294	journal	August 2019
Effective Carrier-Concentration Tuning of SnO ₂ Quantum Dot Electron-Selective Layers for High-Performance Planar Perovskite Solar Cells Yang, Guang; Chen, Cong; Yao, Fang Advanced Materials, Vol. 30, Issue 14 https://doi.org/10.1002/adma.201706023	journal	February 2018
Hydrophobic Polystyrene Passivation Layer for Simultaneously Improved Efficiency and Stability in Perovskite Solar Cells Li, Minghua; Yan, Xiaoqin; Kang, Zhuo ACS Applied Materials & Interfaces, Vol. 10, Issue 22 https://doi.org/10.1021/acsami.8b04776	journal	May 2018
Novel White Electroluminescent Single Polymer Derived from Fluorene and Quinacridone Liu, Jun; Gao, Baoxiang; Cheng, Yanxiang Macromolecules, Vol. 41, Issue 4 https://doi.org/10.1021/ma071235z	journal	February 2008
Enhanced optoelectronic quality of perovskite thin films with hypophosphorous acid for planar heterojunction solar cells Zhang, Wei; Pathak, Sandeep; Sakai, Nobuya Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms10030	journal	November 2015
Synthesis and Solution Processing of a Hydrogen-Bonded Ladder Polymer Zou, Yang; Ji, Xiaozhou; Cai, Jizhe Chem, Vol. 2, Issue 1 https://doi.org/10.1016/j.chempr.2016.12.008	journal	January 2017
Perovskite-polymer composite cross-linker approach for highly-stable and efficient perovskite solar cells Han, Tae-Hee; Lee, Jin-Wook; Choi, Chungseok Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08455-z	journal	January 2019
Rational Design of Dopant‐Free Coplanar D‐π‐D Hole‐Transporting Materials for High‐Performance Perovskite Solar Cells with Fill Factor Exceeding 80% Chen, Yatong; Xu, Xiuwen; Cai, Ning Advanced Energy Materials, Vol. 9, Issue 39 https://doi.org/10.1002/aenm.201901268	journal	August 2019
Observing Defect Passivation of the Grain Boundary with 2‐Aminoterephthalic Acid for Efficient and Stable Perovskite Solar Cells Liu, Zhongze; Cao, Fengren; Wang, Meng Angewandte Chemie International Edition, Vol. 59, Issue 10 https://doi.org/10.1002/anie.201915422	journal	February 2020
Hysteresis Index: A Figure without Merit for Quantifying Hysteresis in Perovskite Solar Cells Habisreutinger, Severin N.; Noel, Nakita K.; Snaith, Henry J. ACS Energy Letters, Vol. 3, Issue 10 https://doi.org/10.1021/acsenergylett.8b01627	journal	September 2018
Interfacial Study To Suppress Charge Carrier Recombination for High Efficiency Perovskite Solar Cells Adhikari, Nirmal; Dubey, Ashish; Khatiwada, Devendra ACS Applied Materials & Interfaces, Vol. 7, Issue 48 https://doi.org/10.1021/acsami.5b09797	journal	November 2015
Defects engineering for high-performance perovskite solar cells Wang, Feng; Bai, Sai; Tress, Wolfgang npj Flexible Electronics, Vol. 2, Issue 1 https://doi.org/10.1038/s41528-018-0035-z	journal	August 2018
Direkte elektrochemische Speicherung und Freisetzung von Kohlendioxid unter der Verwendung eines Industriepigments: Chinacridon Apaydin, Dogukan Hazar; Głowacki, Eric Daniel; Portenkirchner, Engelbert Angewandte Chemie, Vol. 126, Issue 26 https://doi.org/10.1002/ange.201403618	journal	May 2014
Surface optimization to eliminate hysteresis for record efficiency planar perovskite solar cells Yang, Dong; Zhou, Xin; Yang, Ruixia Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE02139E	journal	January 2016
Conjugated Polymer–Assisted Grain Boundary Passivation for Efficient Inverted Planar Perovskite Solar Cells Chen, Wei; Wang, Yingfeng; Pang, Guotao Advanced Functional Materials https://doi.org/10.1002/adfm.201808855	journal	May 2019
The Role of Heteroatoms Leading to Hydrogen Bonds in View of Extended Chemical Stability of Organic Semiconductors Enengl, Christina; Enengl, Sandra; Havlicek, Marek Advanced Functional Materials, Vol. 25, Issue 42 https://doi.org/10.1002/adfm.201503241	journal	October 2015
Hydrogen-Bonded Semiconducting Pigments for Air-Stable Field-Effect Transistors Głowacki, Eric Daniel; Irimia-Vladu, Mihai; Kaltenbrunner, Martin Advanced Materials, Vol. 25, Issue 11 https://doi.org/10.1002/adma.201204039	journal	December 2012
Defect passivation in hybrid perovskite solar cells using quaternary ammonium halide anions and cations Zheng, Xiaopeng; Chen, Bo; Dai, Jun Nature Energy, Vol. 2, Issue 7 https://doi.org/10.1038/nenergy.2017.102	journal	June 2017
Observing Defect Passivation of the Grain Boundary with 2‐Aminoterephthalic Acid for Efficient and Stable Perovskite Solar Cells Liu, Zhongze; Cao, Fengren; Wang, Meng Angewandte Chemie, Vol. 132, Issue 10 https://doi.org/10.1002/ange.201915422	journal	February 2020

Similar Records

Highly Efficient and Stable Perovskite Solar Cells Enabled by Low‐Cost Industrial Organic Pigment Coating

Journal Article · Fri Nov 27 00:00:00 EST 2020 · Angewandte Chemie (International Edition) · OSTI ID:1724438

He, Qingquan; Worku, Michael; Liu, He; +8 more

Enhancing Chemical Stability and Suppressing Ion Migration in CH₃NH₃PbI₃ Perovskite Solar Cells via Direct Backbone Attachment of Polyesters on Grain Boundaries

Journal Article · Fri May 22 00:00:00 EDT 2020 · Chemistry of Materials · OSTI ID:1724438

Zhou, Yuchen; Yin, Yifan; Zuo, Xianghao; +11 more

Eco–Friendly Solvent Engineered CsPbI_2.77Br_0.23 Ink for Large–Area and Scalable High Performance Perovskite Solar Cells

Journal Article · Wed Dec 13 00:00:00 EST 2023 · Advanced Materials · OSTI ID:1724438

Abate, Seid Yimer; Qi, Yifang; Zhang, Qiqi; +7 more

Title: Highly Efficient and Stable Perovskite Solar Cells Enabled by Low‐Cost Industrial Organic Pigment Coating

Citation Formats

References (52)

Similar Records

Related Subjects