Characterizing Olefin Selectivity and Stability of Silver Salts in Ionic Liquids Using Inverse Gas Chromatography

Eor, Philip; Ryoo, Donghyun; Nan, He; Anderson, Jared L.

doi:10.1021/acsomega.0c04854

Characterizing Olefin Selectivity and Stability of Silver Salts in Ionic Liquids Using Inverse Gas Chromatography

Journal Article · Mon Nov 23 00:00:00 EST 2020 · ACS Omega

DOI:https://doi.org/10.1021/acsomega.0c04854· OSTI ID:1724110

Eor, Philip ^[1]; Ryoo, Donghyun ^[1]; Nan, He ^[1]; ^[1]

Ames Laboratory−USDOE and Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States

Separation systems utilizing silver(I) ion-olefin complexation have limitations since silver(I) ions can be poisoned or reduced to metallic silver. Ionic liquids (ILs) are used as solvents for silver(I) ions to facilitate separations since their physico-chemical properties can be easily tuned. To develop separation systems with sustainable olefin selectivity, factors that affect silver(I) ion stability need to be understood. In this study, a total of 13 silver salt/IL mixtures were examined by inverse gas chromatography to identify the effects of silver salt anion and IL cation/anion combination on silver(I) ion stability. The effects of temperature and three different exposure gases on silver(I) ion stability were systematically studied. Exposing silver salt/IL mixtures to hydrogen at high temperatures had a greater effect on decreasing silver(I) ion-olefin complexation. Silver(I) ions from the silver bis[(trifluoromethyl)sulfonyl]imide ([NTf₂^–]) salt were more stable in [NTf₂^–]-containing ILs than in [BF₄^–]-containing ILs. Optimum mixtures exhibited high olefin selectivity and were stable beyond 90 h when exposed to hydrogen gas.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1724110

Alternate ID(s):: OSTI ID: 1735332

Report Number(s):: IS--J-10,359

Journal Information:: ACS Omega, Journal Name: ACS Omega Journal Issue: 48 Vol. 5; ISSN 2470-1343

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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