Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Materials Data on H12PbN3Cl5 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1721977· OSTI ID:1721977
(NH4)3PbCl5 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of twelve ammonium molecules and two PbCl5 ribbons oriented in the (1, 0, 0) direction. In each PbCl5 ribbon, Pb2+ is bonded in a 6-coordinate geometry to six Cl1- atoms. There are a spread of Pb–Cl bond distances ranging from 2.77–3.25 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Pb2+ atom. In the second Cl1- site, Cl1- is bonded in a 2-coordinate geometry to two equivalent Pb2+ atoms. In the third Cl1- site, Cl1- is bonded in a 1-coordinate geometry to one Pb2+ atom.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1721977
Report Number(s):
mp-1212614
Country of Publication:
United States
Language:
English

Similar Records

Materials Data on ZnH12N4Cl4O3 by Materials Project
Dataset · Mon Jun 01 00:00:00 EDT 2020 · OSTI ID:1292562

Materials Data on ZnH12N3Cl5 by Materials Project
Dataset · Wed Apr 29 00:00:00 EDT 2020 · OSTI ID:1287585

Materials Data on Pb3(ClO)2 by Materials Project
Dataset · Mon Jul 20 00:00:00 EDT 2020 · OSTI ID:1262815