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Materials Data on Ta2MoS6 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1719940· OSTI ID:1719940
Ta2MoS6 is Molybdenite-derived structured and crystallizes in the monoclinic Cm space group. The structure is two-dimensional and consists of one Ta2MoS6 sheet oriented in the (0, 0, 1) direction. Ta5+ is bonded to six equivalent S2- atoms to form distorted TaS6 pentagonal pyramids that share edges with three equivalent TaS6 pentagonal pyramids and edges with three equivalent MoS6 pentagonal pyramids. All Ta–S bond lengths are 2.47 Å. Mo2+ is bonded to six equivalent S2- atoms to form distorted MoS6 pentagonal pyramids that share edges with six equivalent TaS6 pentagonal pyramids. All Mo–S bond lengths are 2.44 Å. S2- is bonded in a 3-coordinate geometry to two equivalent Ta5+ and one Mo2+ atom.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1719940
Report Number(s):
mp-1218002
Country of Publication:
United States
Language:
English

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