On the tetragonal forms of KMo{sub 4}O{sub 6}
Journal Article
·
· Journal of Solid State Chemistry
- Rider College, Lawrenceville, NJ (United States)
- State Univ. of New Jersey, Piscataway, NJ (United States)
- California Institute of Technology, Pasadena, CA (United States)
A reexamination of the X-ray diffraction data for the tetragonal form of KMo{sub 4}O{sub 6} prepared by fused salt electrolysis leads to the conclusion that the crystal structure is better described by using space group P4/mbm and not P{bar 4} as previously reported. However, refinement in the new space group does not result in any significant changes in the atomic arrangement. Possible reasons for the significant difference between the c lattice parameter of this form of KMo{sub 4}O{sub 6} and that prepared at high pressures are also discussed.
- OSTI ID:
- 171925
- Journal Information:
- Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 1 Vol. 117; ISSN 0022-4596; ISSN JSSCBI
- Country of Publication:
- United States
- Language:
- English
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