Designing nanoparticle interfaces for inner-sphere catalysis

Ung, David; Murphy, Ian A.; Cossairt, Brandi M.

doi:10.1039/d0dt00785d

Title: Designing nanoparticle interfaces for inner-sphere catalysis

Journal Article · Mon Mar 23 00:00:00 EDT 2020 · Dalton Transactions

DOI:https://doi.org/10.1039/d0dt00785d· OSTI ID:1719105

Ung, David ^[1];

^[1];

^[1]

Univ. of Washington, Seattle, WA (United States)

Interfaces are an intrinsic component of nanoparticle catalysts and play a critical role in directing their function. Our understanding of the complexity of the nanoparticle interface and how to manipulate it at the molecular level has advanced significantly in recent years. Given this, attention is shifting towards the creation of designer nanoparticle interfaces that impact the activity and direct the mechanisms of inner-sphere catalytic reactions. In this perspective, we seek to highlight and contextualize these efforts. First, methods to alter nanoparticle surfaces are presented, including annealing and plasma treating, as well as more mild chemical treatments, including ligand exchange, etching, and addition (via covalent functionalization). Then interfacial chemistry developed to alter catalytic activity, selectivity, and reaction environment will be highlighted. Finally, we look forward to the challenges that remain to be overcome for realizing the true potential of colloidal nanoparticle catalysis.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1719105

Alternate ID(s):: OSTI ID: 1606602

Report Number(s):: PNNL-SA-151764

Journal Information:: Dalton Transactions, Vol. 49, Issue 16; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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