Radiation-induced oxidation of cyclohexane: The mechanism of formation of hydroperoxides
Journal Article
·
· High Energy Chemistry
OSTI ID:171741
- Karpov Institute of Physical Chemistry, Obinsk (Russian Federation)
The formation of hydroperoxides in the {gamma}-radiolysis of cyclohexane was studied over a wide concentration range of molecular oxygen. Features of the radiation-induced oxidation were explained on the basis of an assumption on the pairwise distribution of radicals R and HO{sub 2} produced upon capture of H atoms by molecular oxygen. A simultaneous increase in the yield of hydroperoxides at high concentrations of oxygen is accounted for by the interaction of peroxide radicals with the unrelaxed molecules of the medium.
- OSTI ID:
- 171741
- Journal Information:
- High Energy Chemistry, Journal Name: High Energy Chemistry Journal Issue: 6 Vol. 29; ISSN 0018-1439; ISSN HIECAP
- Country of Publication:
- United States
- Language:
- English
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