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Materials Data on CoH12C2(Br2N)2 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1716980· OSTI ID:1716980
CoBr4(CH3NH3)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight methylammonium molecules and four CoBr4 clusters. In each CoBr4 cluster, Co2+ is bonded in a tetrahedral geometry to four Br1- atoms. There are two shorter (2.40 Å) and two longer (2.42 Å) Co–Br bond lengths. There are four inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a single-bond geometry to one Co2+ atom. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Co2+ atom. In the third Br1- site, Br1- is bonded in a single-bond geometry to one Co2+ atom. In the fourth Br1- site, Br1- is bonded in a single-bond geometry to one Co2+ atom.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1716980
Report Number(s):
mp-1195995
Country of Publication:
United States
Language:
English

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