Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Designing Advanced In Situ Electrode/Electrolyte Interphases for Wide Temperature Operation of 4.5 V Li||LiCoO2 Batteries

Journal Article · · Advanced Materials
 [1];  [2];  [3];  [2];  [2];  [2];  [2];  [2];  [2];  [2];  [3];  [2];  [2];  [2]
  1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Univ. of Science and Technology of China, Hefei (China)
  2. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States)
+ Show Author Affiliations
High-energy-density batteries with a LiCoO2 (LCO) cathode are of significant importance to the energy-storage market, especially for portable electronics. However, their development is greatly limited by the inferior performance under high voltages and challenging temperatures. In this paper, highly stable lithium (Li) metal batteries with LCO cathode, through the design of in situ formed, stable electrode/electrolyte interphases on both the Li anode and the LCO cathode, with an advanced electrolyte, are reported. The LCO cathode can deliver a high specific capacity of ≈190 mAh g-1 and show greatly improved cell performances under a high charge voltage of 4.5 V (even up to 4.55 V) and a wide temperature range from -30 to 55 °C. This work points out a promising approach for developing Li||LCO batteries for practical applications. This approach can also be used to improve the high-voltage performance of other batteries in a broad temperature range.
Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
Grant/Contract Number:
AC05-76RL01830; SC0012704
OSTI ID:
1716834
Alternate ID(s):
OSTI ID: 1804165
OSTI ID: 1734639
OSTI ID: 1760510
Report Number(s):
BNL-220627-2020--JAAM
Journal Information:
Advanced Materials, Journal Name: Advanced Materials Journal Issue: 49 Vol. 32; ISSN 0935-9648
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

References (38)

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes journal March 2018
Differentiated Lithium Salt Design for Multilayered PEO Electrolyte Enables a High‐Voltage Solid‐State Lithium Metal Battery journal September 2019
Surface Engineering Strategies of Layered LiCoO 2 Cathode Material to Realize High-Energy and High-Voltage Li-Ion Cells journal October 2016
High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes journal July 2019
Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range journal April 2020
Enabling a Durable Electrochemical Interface via an Artificial Amorphous Cathode Electrolyte Interphase for Hybrid Solid/Liquid Lithium‐Metal Batteries journal February 2020
On the capacity fading of LiCoO2 intercalation electrodes: journal October 2002
Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries journal January 2018
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries journal August 2018
Enhanced 4.5 V/55 °C cycling performance of LiCoO2 cathode via LiAlO2LiCo1-xAlxO2 double-layer coatings journal February 2019
Cuprite-coated Cu foam skeleton host enabling lateral growth of lithium dendrites for advanced Li metal batteries journal September 2019
Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions journal July 2019
Fluorinated Solid-Electrolyte Interphase in High-Voltage Lithium Metal Batteries journal November 2019
Realizing long-term cycling stability and superior rate performance of 4.5 V–LiCoO2 by aluminum doped zinc oxide coating achieved by a simple wet-mixing method journal September 2020
Wettable carbon felt framework for high loading Li-metal composite anode journal June 2019
Before Li Ion Batteries journal November 2018
Chemical States of Overcharged LiCoO 2 Particle Surfaces and Interiors Observed Using Electron Energy-Loss Spectroscopy journal June 2015
Coupled LiPF 6 Decomposition and Carbonate Dehydrogenation Enhanced by Highly Covalent Metal Oxides in High-Energy Li-Ion Batteries journal October 2018
Functional Electrolyte of Fluorinated Ether and Ester for Stabilizing Both 4.5 V LiCoO 2 Cathode and Lithium Metal Anode journal January 2020
Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes journal January 2018
High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries journal March 2019
Reviving the lithium metal anode for high-energy batteries journal March 2017
Electrochemical surface passivation of LiCoO2 particles at ultrahigh voltage and its applications in lithium-based batteries journal November 2018
A retrospective on lithium-ion batteries journal May 2020
Approaching the capacity limit of lithium cobalt oxide in lithium ion batteries via lanthanum and aluminium doping journal June 2018
Pathways for practical high-energy long-cycling lithium metal batteries journal February 2019
Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization journal September 2019
Injection of oxygen vacancies in the bulk lattice of layered cathodes journal April 2019
A deep study of the protection of Lithium Cobalt Oxide with polymer surface modification at 4.5 V high voltage journal January 2018
Lithium metal anodes for rechargeable batteries journal January 2014
A multifunctional polymer electrolyte enables ultra-long cycle-life in a high-voltage lithium metal battery journal January 2018
Reviving lithium cobalt oxide-based lithium secondary batteries-toward a higher energy density journal January 2018
Gradient-morph LiCoO 2 single crystals with stabilized energy density above 3400 W h L −1 journal January 2020
Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries journal January 2018
Formation of SEI on Cycled Lithium-Ion Battery Cathodes: Soft X-Ray Absorption Study journal January 2002
Perspective—Fluorinating Interphases journal December 2018
Probing Surface Chemistry Changes Using LiCoO 2 -only Electrodes in Li-Ion Batteries journal January 2018
Polymer Electrolyte Enlightens Wide-Temperature 4.45 V-Class LiCoO 2 /Li Metal Battery journal January 2019

Similar Records

Designing Advanced In Situ Electrode/Electrolyte Interphases for Wide Temperature Operation of 4.5 V Li || LiCoO2 Batteries
Journal Article · Wed Dec 09 23:00:00 EST 2020 · Advanced Materials · OSTI ID:1734639
Stabilizing electrode–electrolyte interfaces to realize high-voltage Li||LiCoO2 batteries by a sulfonamide-based electrolyte
Journal Article · Wed Oct 20 20:00:00 EDT 2021 · Energy & Environmental Science · OSTI ID:1830205

Related Subjects

25 ENERGY STORAGE
cathode/electrolyte interphases
ether electrolytes
high-voltage LiCoO2
lithium metal batteries