General Techno-Economic Analysis of CO2 Electrolysis Systems

Jouny, Matthew; Luc, Wesley; Jiao, Feng

doi:10.1021/acs.iecr.7b03514

General Techno-Economic Analysis of CO₂ Electrolysis Systems

Journal Article · Fri Jan 19 00:00:00 EST 2018 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/acs.iecr.7b03514· OSTI ID:1712664

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Univ. of Delaware, Newark, DE (United States); University of Delaware
Univ. of Delaware, Newark, DE (United States)

The electrochemical reduction of carbon dioxide (CO₂) has received significant attention in academic research, although the techno-economic prospects of the technology for the large-scale production of chemicals are unclear. In this work, we briefly reviewed the current state-of-the-art CO₂ reduction figures of merit, and performed an economic analysis of a generalized CO₂ electrolyzer system for the production of 100 tons/day of various CO₂ reduction products. While carbon monoxide and formic acid were the most economically favorable products under current conditions, higher-order alcohols such as ethanol and n-propanol could be highly promising if reasonable electrocatalytic performance benchmarks were achieved. Furthermore, we established performance targets such that if these targets are achieved, electrochemical CO₂ reduction for fuels and chemicals production can become a profitable option as part of the growing renewable energy infrastructure.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: FE0029868

OSTI ID:: 1712664

Alternate ID(s):: OSTI ID: 1539065

Journal Information:: Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 6 Vol. 57; ISSN 0888-5885

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Unveiling Electrochemical Reaction Pathways of CO ₂ Reduction to C _N Species at S‐Vacancies of MoS ₂ Kang, Sungwoo; Han, Seungwu; Kang, Youngho ChemSusChem, Vol. 12, Issue 12 https://doi.org/10.1002/cssc.201900779	journal	May 2019
A General Technoeconomic Model for Evaluating Emerging Electrolytic Processes Orella, Michael J.; Brown, Steven M.; Leonard, McLain E. Energy Technology, Vol. 8, Issue 11 https://doi.org/10.1002/ente.201900994	journal	December 2019
Advances and challenges in modeling solvated reaction mechanisms for renewable fuels and chemicals Basdogan, Yasemin; Maldonado, Alex M.; Keith, John A. WIREs Computational Molecular Science, Vol. 10, Issue 2 https://doi.org/10.1002/wcms.1446	journal	August 2019
Electroreduction of carbon dioxide to formate at high current densities using tin and tin oxide gas diffusion electrodes Sen, Sujat; Brown, Steven M.; Leonard, McLain Journal of Applied Electrochemistry, Vol. 49, Issue 9 https://doi.org/10.1007/s10800-019-01332-z	journal	July 2019
pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper Liu, Xinyan; Schlexer, Philomena; Xiao, Jianping Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-018-07970-9	journal	January 2019
Efficient upgrading of CO to C3 fuel using asymmetric C-C coupling active sites Wang, Xue; Wang, Ziyun; Zhuang, Tao-Tao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13190-6	journal	November 2019
Formation of carbon–nitrogen bonds in carbon monoxide electrolysis Jouny, Matthew; Lv, Jing-Jing; Cheng, Tao Nature Chemistry, Vol. 11, Issue 9 https://doi.org/10.1038/s41557-019-0312-z	journal	August 2019
Continuous production of pure liquid fuel solutions via electrocatalytic CO2 reduction using solid-electrolyte devices Xia, Chuan; Zhu, Peng; Jiang, Qiu Nature Energy, Vol. 4, Issue 9 https://doi.org/10.1038/s41560-019-0451-x	journal	September 2019
Growth of E. coli on formate and methanol via the reductive glycine pathway Kim, Seohyoung; Lindner, Steffen N.; Aslan, Selçuk Nature Chemical Biology, Vol. 16, Issue 5 https://doi.org/10.1038/s41589-020-0473-5	journal	February 2020
High-rate electroreduction of carbon monoxide to multi-carbon products Jouny, Matthew; Luc, Wesley; Jiao, Feng Nature Catalysis, Vol. 1, Issue 10 https://doi.org/10.1038/s41929-018-0133-2	journal	August 2018
Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate Luc, Wesley; Fu, Xianbiao; Shi, Jianjian Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0269-8	journal	April 2019
Making quantitative sense of electromicrobial production Claassens, Nico J.; Cotton, Charles A. R.; Kopljar, Dennis Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0272-0	journal	May 2019
Designing materials for electrochemical carbon dioxide recycling Ross, Michael B.; De Luna, Phil; Li, Yifan Nature Catalysis, Vol. 2, Issue 8 https://doi.org/10.1038/s41929-019-0306-7	journal	July 2019
Constraining CO coverage on copper promotes high-efficiency ethylene electroproduction Li, Jun; Wang, Ziyun; McCallum, Christopher Nature Catalysis, Vol. 2, Issue 12 https://doi.org/10.1038/s41929-019-0380-x	journal	November 2019
Cooperative CO2-to-ethanol conversion via enriched intermediates at molecule–metal catalyst interfaces Li, Fengwang; Li, Yuguang C.; Wang, Ziyun Nature Catalysis, Vol. 3, Issue 1 https://doi.org/10.1038/s41929-019-0383-7	journal	December 2019
Carbon monoxide electroreduction as an emerging platform for carbon utilization Jouny, Matthew; Hutchings, Gregory S.; Jiao, Feng Nature Catalysis, Vol. 2, Issue 12 https://doi.org/10.1038/s41929-019-0388-2	journal	December 2019
Combined high alkalinity and pressurization enable efficient CO ₂ electroreduction to CO Gabardo, Christine M.; Seifitokaldani, Ali; Edwards, Jonathan P. Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/c8ee01684d	journal	January 2018
CO ₂ reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions Burdyny, Thomas; Smith, Wilson A. Energy & Environmental Science, Vol. 12, Issue 5 https://doi.org/10.1039/c8ee03134g	journal	January 2019
The importance of morphology on the activity of lead cathodes for the reduction of carbon dioxide to formate Pander, James E.; Lum, Jeremy Wei Jian; Yeo, Boon Siang Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta10752a	journal	January 2019
An alkaline polymer electrolyte CO ₂ electrolyzer operated with pure water Yin, Zhenglei; Peng, Hanqing; Wei, Xing Energy & Environmental Science, Vol. 12, Issue 8 https://doi.org/10.1039/c9ee01204d	journal	January 2019
Formic acid, a biomass-derived source of energy and hydrogen for biomass upgrading Valentini, Federica; Kozell, Vadym; Petrucci, Chiara Energy & Environmental Science, Vol. 12, Issue 9 https://doi.org/10.1039/c9ee01747j	journal	January 2019
Transforming the carbon economy: challenges and opportunities in the convergence of low-cost electricity and reductive CO ₂ utilization Grim, R. Gary; Huang, Zhe; Guarnieri, Michael T. Energy & Environmental Science, Vol. 13, Issue 2 https://doi.org/10.1039/c9ee02410g	journal	January 2020
Oxygen-tolerant electroproduction of C ₂ products from simulated flue gas Xu, Yi; Edwards, Jonathan P.; Zhong, Junjie Energy & Environmental Science, Vol. 13, Issue 2 https://doi.org/10.1039/c9ee03077h	journal	January 2020
Surface reconstruction of AgPd nanoalloy particles during the electrocatalytic formate oxidation reaction Guo, Longfei; Chen, Fuyi; Jin, Tao Nanoscale, Vol. 12, Issue 5 https://doi.org/10.1039/c9nr09660d	journal	January 2020
A perspective on practical solar to carbon monoxide production devices with economic evaluation Chae, Sang Youn; Lee, Si Young; Han, Sung Gyu Sustainable Energy & Fuels, Vol. 4, Issue 1 https://doi.org/10.1039/c9se00647h	journal	January 2020
Achieving highly efficient CO 2 to CO electroreduction exceeding 300 mA cm −2 with single-atom nickel electrocatalysts Jeong, Hui-Yun; Balamurugan, Mani; Choutipalli, Venkata Surya Kumar Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta02405k	journal	January 2019
Electrochemical impedance spectroscopy as a performance indicator of water dissociation in bipolar membranes Blommaert, Marijn A.; Vermaas, David A.; Izelaar, Boaz Journal of Materials Chemistry A, Vol. 7, Issue 32 https://doi.org/10.1039/c9ta04592a	journal	January 2019
Selective reduction of CO to acetaldehyde with CuAg electrocatalysts Wang, Lei; Higgins, Drew C.; Ji, Yongfei Proceedings of the National Academy of Sciences, Vol. 117, Issue 23 https://doi.org/10.1073/pnas.1821683117	journal	January 2020
Current achievements and the future direction of electrochemical CO 2 reduction: A short review Lee, Mi-Young; Park, Ki Tae; Lee, Wonhee Critical Reviews in Environmental Science and Technology https://doi.org/10.1080/10643389.2019.1631991	journal	June 2019
What would it take for renewably powered electrosynthesis to displace petrochemical processes? De Luna, Phil; Hahn, Christopher; Higgins, Drew Science, Vol. 364, Issue 6438 https://doi.org/10.1126/science.aav3506	journal	April 2019
CO ₂ electrolysis to multicarbon products at activities greater than 1 A cm ⁻² García de Arquer, F. Pelayo; Dinh, Cao-Thang; Ozden, Adnan Science, Vol. 367, Issue 6478 https://doi.org/10.1126/science.aay4217	journal	February 2020
Process intensification technologies for CO2 capture and conversion – a review Adamu, Abdullahi; Russo-Abegão, Fernando; Boodhoo, Kamelia BMC Chemical Engineering, Vol. 2, Issue 1 https://doi.org/10.1186/s42480-019-0026-4	journal	January 2020
Towards Higher Rate Electrochemical CO2 Conversion: From Liquid-Phase to Gas-Phase Systems Song, Jun; Song, Hakhyeon; Kim, Beomil Catalysts, Vol. 9, Issue 3 https://doi.org/10.3390/catal9030224	journal	March 2019

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
carbon dioxide
electrocatalysts
electrochemical reduction
inorganic carbon compounds
organic acids
oxides