Transition between Different Diffusion Regimes and Its Relationship with Structural Properties in Nafion by High Field Diffusion NMR in Combination with Small-Angle X-ray and Neutron Scattering

Berens, Samuel J.; Yahya, Ahmad; Fang, Junchuan; Angelopoulos, Anastasios; Nickels, Jonathan D.; Vasenkov, Sergey

doi:10.1021/acs.jpcb.0c07249

Title: Transition between Different Diffusion Regimes and Its Relationship with Structural Properties in Nafion by High Field Diffusion NMR in Combination with Small-Angle X-ray and Neutron Scattering

Journal Article · Fri Dec 04 00:00:00 EST 2020 · J. Phys. Chem. B

DOI:https://doi.org/10.1021/acs.jpcb.0c07249· OSTI ID:1712469

Berens, Samuel J.; Yahya, Ahmad; Fang, Junchuan; Angelopoulos, Anastasios; Nickels, Jonathan D.; Vasenkov, Sergey ^[1]

UCIN

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: National Science Foundation (NSF)

OSTI ID:: 1712469

Journal Information:: J. Phys. Chem. B, Vol. 124, Issue (40) ; 09, 2020

Country of Publication:: United States

Language:: ENGLISH

References (43)

Review of the proton exchange membranes for fuel cell applications Peighambardoust, S. J.; Rowshanzamir, S.; Amjadi, M. International Journal of Hydrogen Energy, Vol. 35, Issue 17 https://doi.org/10.1016/j.ijhydene.2010.05.017	journal	September 2010
Recent Development of Polymer Electrolyte Membranes for Fuel Cells Zhang, Hongwei; Shen, Pei Kang Chemical Reviews, Vol. 112, Issue 5 https://doi.org/10.1021/cr200035s	journal	February 2012
Progress in Flow Battery Research and Development Skyllas-Kazacos, M.; Chakrabarti, M. H.; Hajimolana, S. A. Journal of The Electrochemical Society, Vol. 158, Issue 8, p. R55-R79 https://doi.org/10.1149/1.3599565	journal	June 2011
Selectivity of ion exchange membranes: A review Luo, Tao; Abdu, Said; Wessling, Matthias Journal of Membrane Science, Vol. 555 https://doi.org/10.1016/j.memsci.2018.03.051	journal	June 2018
Portable method of measuring gaseous acetone concentrations Worrall, Adam D.; Bernstein, Jonathan A.; Angelopoulos, Anastasios P. Talanta, Vol. 112 https://doi.org/10.1016/j.talanta.2013.03.052	journal	August 2013
Water-Resistant Polymeric Acid Membrane Catalyst for Acetone Detection in the Exhaled Breath of Diabetics Worrall, Adam D.; Qian, Zexin; Bernstein, Jonathan A. Analytical Chemistry, Vol. 90, Issue 3 https://doi.org/10.1021/acs.analchem.7b03808	journal	January 2018
Parallel cylindrical water nanochannels in Nafion fuel-cell membranes Schmidt-Rohr, Klaus; Chen, Qiang Nature Materials, Vol. 7, Issue 1 https://doi.org/10.1038/nmat2074	journal	December 2007
The morphology in nafion perfluorinated membrane products, as determined by wide- and small-angle x-ray studies Gierke, T. D.; Munn, G. E.; Wilson, F. C. Journal of Polymer Science: Polymer Physics Edition, Vol. 19, Issue 11 https://doi.org/10.1002/pol.1981.180191103	journal	November 1981
Review and Critical Analyses of Theories of Aggregation in Ionomers Mauritz, Kenneth A. Journal of Macromolecular Science, Part C: Polymer Reviews, Vol. 28, Issue 1 https://doi.org/10.1080/15583728808085375	journal	January 1988
Mesoscale simulation of morphology in hydrated perfluorosulfonic acid membranes Wescott, James T.; Qi, Yue; Subramanian, Lalitha The Journal of Chemical Physics, Vol. 124, Issue 13 https://doi.org/10.1063/1.2177649	journal	April 2006
New Insights into Perfluorinated Sulfonic-Acid Ionomers Kusoglu, Ahmet; Weber, Adam Z. Chemical Reviews, Vol. 117, Issue 3 https://doi.org/10.1021/acs.chemrev.6b00159	journal	January 2017
Nanoscale properties of polymer fuel cell materials-A selected review Hiesgen, Renate; Wehl, Ines; Aleksandrova, Elena International Journal of Energy Research https://doi.org/10.1002/er.1661	journal	January 2009
A unified morphological description of Nafion membranes from SAXS and mesoscale simulations Elliott, James A.; Wu, Dongsheng; Paddison, Stephen J. Soft Matter, Vol. 7, Issue 15 https://doi.org/10.1039/c1sm00002k	journal	January 2011
Water Uptake of Perfluorosulfonic Acid Membranes from Liquid Water and Water Vapor Hinatsu, James T. Journal of The Electrochemical Society, Vol. 141, Issue 6 https://doi.org/10.1149/1.2054951	journal	January 1994
Water and Methanol Uptakes in Nafion Membranes and Membrane Effects on Direct Methanol Cell Performance Ren, X.; Springer, T. E.; Gottesfeld, S. Journal of The Electrochemical Society, Vol. 147, Issue 1 https://doi.org/10.1149/1.1393161	journal	January 2000
Anomalous, Multistage Liquid Water Diffusion and Ionomer Swelling Kinetics in Nafion and Nafion Nanocomposites Balwani, Apoorv; Davis, Eric M. ACS Applied Polymer Materials, Vol. 2, Issue 1 https://doi.org/10.1021/acsapm.9b00866	journal	December 2019
An NMR spectroscopic study of water and methanol transport properties in DMFC composite membranes: Influence on the electrochemical behaviour Baglio, V.; Aricò, A. S.; Antonucci, V. Journal of Power Sources, Vol. 163, Issue 1 https://doi.org/10.1016/j.jpowsour.2006.01.065	journal	December 2006
NMR investigation of water and methanol mobility in nanocomposite fuel cell membranes Nicotera, Isabella; Khalfan, Ameesh; Goenaga, Gabriel Ionics, Vol. 14, Issue 3 https://doi.org/10.1007/s11581-007-0178-8	journal	November 2007
Proton Dynamics of Nafion and Nafion/SiO ₂ Composites by Solid State NMR and Pulse Field Gradient NMR Ye, G.; Hayden, C. A.; Goward, G. R. Macromolecules, Vol. 40, Issue 5 https://doi.org/10.1021/ma0621876	journal	March 2007
Anisotropy of Water Self-Diffusion in a Nafion Membrane under Traction Klein, Mathieu; Perrin, Jean-Christophe; Leclerc, Sébastien Macromolecules, Vol. 46, Issue 23 https://doi.org/10.1021/ma401511t	journal	November 2013
Self-Diffusion of Ions at Different Time Scales in a Porous and Charged Medium: The Nafion Membrane Rollet, Anne-Laure; Simonin, Jean-Pierre; Turq, Pierre The Journal of Physical Chemistry B, Vol. 105, Issue 19 https://doi.org/10.1021/jp0023462	journal	May 2001
Diffusion and Interfacial Transport of Water in Nafion Zhao, Qiao; Majsztrik, Paul; Benziger, Jay The Journal of Physical Chemistry B, Vol. 115, Issue 12 https://doi.org/10.1021/jp1112125	journal	March 2011
Water sub-diffusion in membranes for fuel cells Berrod, Quentin; Hanot, Samuel; Guillermo, Armel Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-08746-9	journal	August 2017
Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes Zawodzinski, Thomas A.; Neeman, Michal; Sillerud, Laurel O. The Journal of Physical Chemistry, Vol. 95, Issue 15 https://doi.org/10.1021/j100168a060	journal	July 1991
Role of water states on water uptake and proton transport in Nafion using molecular simulations and bimodal network Hwang, Gi Suk; Kaviany, Massoud; Gostick, Jeffrey T. Polymer, Vol. 52, Issue 12 https://doi.org/10.1016/j.polymer.2011.03.056	journal	May 2011
Transport in Proton Conductors for Fuel-Cell Applications: Simulations, Elementary Reactions, and Phenomenology Kreuer, Klaus-Dieter; Paddison, Stephen J.; Spohr, Eckhard Chemical Reviews, Vol. 104, Issue 10 https://doi.org/10.1021/cr020715f	journal	October 2004
Nanophase segregation and water dynamics in hydrated Nafion: Molecular modeling and experimental validation Malek, Kourosh; Eikerling, Michael; Wang, Qianpu The Journal of Chemical Physics, Vol. 129, Issue 20 https://doi.org/10.1063/1.3000641	journal	November 2008
Determination of a Micron-Scale Restricted Structure in a Perfluorinated Membrane from Time-Dependent Self-Diffusion Measurements Ohkubo, T.; Kidena, K.; Ohira, A. Macromolecules, Vol. 41, Issue 22 https://doi.org/10.1021/ma801331e	journal	November 2008
Evidence of Temperature-Induced Subdiffusion of Water on the Micrometer Scale in a Nafion Membrane Casieri, Cinzia; Monaco, Antonina; De Luca, Francesco Macromolecules, Vol. 43, Issue 2 https://doi.org/10.1021/ma902323t	journal	December 2009
Deconvolution and Estimation of Water Diffusion in Sulfonated Polyethersulfone Membranes Using Diffusion-Weighted Inversion Recovery. Ohkubo, Takahiro; Ohira, Akihiro; Iwadate, Yasuhiko The Journal of Physical Chemistry Letters, Vol. 3, Issue 8 https://doi.org/10.1021/jz3002458	journal	April 2012
Correlating morphology, proton conductivity, and water transport in polyelectrolyte-fluoropolymer blend membranes Hou, Jianbo; Li, Jing; Mountz, David Journal of Membrane Science, Vol. 448 https://doi.org/10.1016/j.memsci.2013.08.019	journal	December 2013
Transesterification of triacetin with methanol on Nafion® acid resins Lopez, D.; Goodwinjr, J.; Bruce, D. Journal of Catalysis, Vol. 245, Issue 2 https://doi.org/10.1016/j.jcat.2006.10.027	journal	January 2007
Blood Ketone Bodies and Breath Acetone Analysis and Their Correlations in Type 2 Diabetes Mellitus Saasa, Valentine; Beukes, Mervyn; Lemmer, Yolandy Diagnostics, Vol. 9, Issue 4 https://doi.org/10.3390/diagnostics9040224	journal	December 2019
Real-time optical sensing of exhaled acetone concentration utilizing non-Fickian Nafion diffusion inside a flow-through sample chamber Badmaarag, Ulzii-Orshikh; Bernstein, Jonathan A.; Shekarriz, Reza Sensing and Bio-Sensing Research, Vol. 29 https://doi.org/10.1016/j.sbsr.2020.100373	journal	August 2020
Relationship between mixed and pure gas self-diffusion for ethane and ethene in ZIF-8/6FDA-DAM mixed-matrix membrane by pulsed field gradient NMR Mueller, Robert; Hariharan, Venkat; Zhang, Chen Journal of Membrane Science, Vol. 499 https://doi.org/10.1016/j.memsci.2015.10.036	journal	February 2016
Relationship between long-range diffusion and diffusion in the ZIF-8 and polymer phases of a mixed-matrix membrane by high field NMR diffusometry Mueller, Robert; Zhang, Suihua; Zhang, Chen Journal of Membrane Science, Vol. 477 https://doi.org/10.1016/j.memsci.2014.12.015	journal	March 2015
Diffusion in Nanoporous Materials Kärger, Jörg; Ruthven, Douglas M.; Theodorou, Doros N. https://doi.org/10.1002/9783527651276	book	April 2012
Effects of microgeometry and surface relaxation on NMR pulsed-field-gradient experiments: Simple pore geometries Mitra, Partha P.; Sen, Pabitra N. Physical Review B, Vol. 45, Issue 1 https://doi.org/10.1103/physrevb.45.143	journal	January 1992
Transient diffusion in a system partitioned by permeable barriers. Application to NMR measurements with a pulsed field gradient Tanner, J. E. The Journal of Chemical Physics, Vol. 69, Issue 4 https://doi.org/10.1063/1.436751	journal	August 1978
Subsecond Morphological Changes in Nafion during Water Uptake Detected by Small-Angle X-ray Scattering Kusoglu, Ahmet; Modestino, Miguel A.; Hexemer, Alexander ACS Macro Letters, Vol. 1, Issue 1 https://doi.org/10.1021/mz200015c	journal	November 2011
The kinetics of water sorption in Nafion membranes: a small-angle neutron scattering study Gebel, Gérard; Lyonnard, Sandrine; Mendil-Jakani, Hakima Journal of Physics: Condensed Matter, Vol. 23, Issue 23 https://doi.org/10.1088/0953-8984/23/23/234107	journal	May 2011
SANS Study of the Effects of Water Vapor Sorption on the Nanoscale Structure of Perfluorinated Sulfonic Acid (NAFION) Membranes Kim, Man-Ho; Glinka, Charles J.; Grot, Stephen A. Macromolecules, Vol. 39, Issue 14 https://doi.org/10.1021/ma060576u	journal	July 2006
Insight into the multiscale structure of pre-stretched recast Nafion® membranes: Focus on the crystallinity features Mendil-Jakani, Hakima; Pouget, Stéphanie; Gebel, Gérard Polymer, Vol. 63 https://doi.org/10.1016/j.polymer.2015.02.046	journal	April 2015

Similar Records

Tertiary and quaternary structural differences between two genetic variants of bovine casein by small-angle X-ray scattering

Journal Article · Tue Jan 01 00:00:00 EST 1991 · Archives of Biochemistry and Biophysics; (USA) · OSTI ID:1712469

Pessen, H; Kumosinski, T F; Farrell, Jr, H M; +1 more

Alkyl Chain Length and Temperature Effects on Structural Properties of Pyrrolidinium-Based Ionic Liquids: A Combined Atomistic Simulation and Small-Angle X-ray Scattering Study.

Journal Article · Sat Jan 01 00:00:00 EST 2011 · Journal of Physical Chemistry Letters · OSTI ID:1712469

Li, Song; Banuelos, Jose Leo; Guo, Jianchang; +6 more

Alkyl Chain Length and Temperature Effects on Structural Properties of Pyrrolidinium-Based Ionic Liquids: A Combined Atomistic Simulation and Small-Angle X-ray Scattering Study

Journal Article · Thu Jan 05 00:00:00 EST 2012 · Journal of Physical Chemistry Letters · OSTI ID:1712469

Li, Song; Bañuelos, José Leobardo; Guo, Jianchang; +7 more

Title: Transition between Different Diffusion Regimes and Its Relationship with Structural Properties in Nafion by High Field Diffusion NMR in Combination with Small-Angle X-ray and Neutron Scattering

Citation Formats

References (43)

Similar Records

Related Subjects