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Title: Prediction of Crack Propagation Paths in the Unit Cell of a SOFC Stacks

Journal Article · · International Journal of Mechanics and Materials in Design

Crack deflection and penetration paths at interfaces of the multilayer structures in a solid oxide fuel cell (SOFC) under thermomechanical loading are predicted. An asymptotic approach was applied to a three layer structure typical of an SOFC unit cell consisting of the anode, electrolyte and cathode. Residual thermal stress due to thermal cycling during operation of the fuel cell was taken into consideration for the crack propagation path prediction. Finite element analysis was utilized to determine the energy release rate and possible crack propagation paths. Influence of thermal and mechanical loads on crack propagation paths was compared. An energy criterion as a function of crack length was used for the prediction of possible crack extension, and an analysis of the influence of crack length on the crack propagation path is presented. This work on prediction of crack propagation paths in SOFC materials, based on thermomechanical properties and geometry, will provide a powerful tool for guidance on how to tailor gradient porous microstructures of electrodes to improve toughness and performance of fuel cell components.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1710222
Report Number(s):
PNNL-SA-90994
Journal Information:
International Journal of Mechanics and Materials in Design, Vol. 5
Country of Publication:
United States
Language:
English

References (8)

Crack deflection at an interface between dissimilar elastic materials journal January 1989
Kinking of a Crack Out of an Interface journal June 1989
Fracture energy and crack growth in surface treated Yttria stabilized Zirconia for SOFC applications journal August 2002
Mode III near and far fields for a crack lying in or along a joint journal May 2000
Prediction of crack deflection in porous/dense ceramic laminates journal January 2006
A revisited criterion for crack deflection at an interface in a brittle bimaterial journal September 2001
Mechanical and Electrical Properties of Porous Lanthanum Strontium Manganite at Operating Temperature [作動温度下での多孔質ランタンストロンチウムマンガナイトの機械的および電気的特性] journal January 2003
Elastic properties of ceramic oxides used in solid oxide fuel cells (SOFC) journal January 1997

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