Materials Data on Pd(NCl)2 by Materials Project
Pd(NCl)2 crystallizes in the triclinic P1 space group. The structure is one-dimensional and consists of one Pd(NCl)2 ribbon oriented in the (1, 0, 0) direction. Pd2+ is bonded in a distorted rectangular see-saw-like geometry to four N atoms. There are three shorter (2.01 Å) and one longer (2.02 Å) Pd–N bond lengths. There are two inequivalent N sites. In the first N site, N is bonded in a trigonal planar geometry to two equivalent Pd2+ and one Cl1- atom. The N–Cl bond length is 1.66 Å. In the second N site, N is bonded in a trigonal planar geometry to two equivalent Pd2+ and one Cl1- atom. The N–Cl bond length is 1.66 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one N atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one N atom.
- Research Organization:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Contributing Organization:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231
- OSTI ID:
- 1708194
- Report Number(s):
- mp-1179931
- Country of Publication:
- United States
- Language:
- English
Similar Records
Materials Data on Pd(NCl)2 by Materials Project
Materials Data on Pd(NCl)2 by Materials Project
Materials Data on Ti(NCl)3 by Materials Project
Dataset
·
Sun May 03 00:00:00 EDT 2020
·
OSTI ID:1723226
Materials Data on Pd(NCl)2 by Materials Project
Dataset
·
Sun May 03 00:00:00 EDT 2020
·
OSTI ID:1675669
Materials Data on Ti(NCl)3 by Materials Project
Dataset
·
Tue Jul 14 00:00:00 EDT 2020
·
OSTI ID:1276504