Oxidation of Ammonia with Molecular Complexes

Dunn, Peter L.; Cook, Brian J.; Johnson, Samantha I.; Appel, Aaron M.; Bullock, R. Morris

doi:10.1021/jacs.0c08269

Title: Oxidation of Ammonia with Molecular Complexes

Journal Article · Fri Sep 25 00:00:00 EDT 2020 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.0c08269· OSTI ID:1706682

^[1]; Cook, Brian J. ^[1];

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Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Center for Molecular Electrocatalysis

Oxidation of ammonia by molecular complexes is a burgeoning area of research. Several scientific challenges underpin these efforts, requiring a fundamental understanding of individual reactions steps, particularly for cleavage of N-H bonds and formation of N-N bonds. Overall, this perspective evaluates the challenges of designing molecular catalysts for oxidation of ammonia, and highlights recent key contributions to realizing the goals of viable energy storage and retrieval based on the N-H bonds of ammonia in a carbon-free energy cycle.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1706682

Report Number(s):: PNNL-SA-155069

Journal Information:: Journal of the American Chemical Society, Vol. 142, Issue 42; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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catalysis

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