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Materials Data on Eu4Zn51 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1704764· OSTI ID:1704764
Eu4Zn51 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. there are two inequivalent Eu sites. In the first Eu site, Eu is bonded in a 12-coordinate geometry to twenty-four Zn atoms. There are a spread of Eu–Zn bond distances ranging from 3.50–3.56 Å. In the second Eu site, Eu is bonded in a 6-coordinate geometry to twenty-four Zn atoms. There are a spread of Eu–Zn bond distances ranging from 3.50–3.54 Å. There are ten inequivalent Zn sites. In the first Zn site, Zn is bonded in a 11-coordinate geometry to two Eu and nine Zn atoms. There are a spread of Zn–Zn bond distances ranging from 2.54–2.87 Å. In the second Zn site, Zn is bonded in a 12-coordinate geometry to two Eu and ten Zn atoms. There are a spread of Zn–Zn bond distances ranging from 2.51–2.95 Å. In the third Zn site, Zn is bonded in a 11-coordinate geometry to two equivalent Eu and nine Zn atoms. There are a spread of Zn–Zn bond distances ranging from 2.52–2.69 Å. In the fourth Zn site, Zn is bonded in a 12-coordinate geometry to two equivalent Eu and ten Zn atoms. There are a spread of Zn–Zn bond distances ranging from 2.52–2.74 Å. In the fifth Zn site, Zn is bonded in a 12-coordinate geometry to two equivalent Eu and ten Zn atoms. There are a spread of Zn–Zn bond distances ranging from 2.63–2.94 Å. In the sixth Zn site, Zn is bonded in a 12-coordinate geometry to two equivalent Eu and ten Zn atoms. There are a spread of Zn–Zn bond distances ranging from 2.62–2.93 Å. In the seventh Zn site, Zn is bonded in a 12-coordinate geometry to two Eu and ten Zn atoms. There are a spread of Zn–Zn bond distances ranging from 2.64–2.74 Å. In the eighth Zn site, Zn is bonded in a 12-coordinate geometry to two Eu and ten Zn atoms. The Zn–Zn bond length is 2.64 Å. In the ninth Zn site, Zn is bonded in a cuboctahedral geometry to twelve Zn atoms. In the tenth Zn site, Zn is bonded in a cuboctahedral geometry to twelve Zn atoms.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1704764
Report Number(s):
mp-1227723
Country of Publication:
United States
Language:
English

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