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Title: Organic aerogels from the sol-gel polymerization of phenolic-furfural mixtures

Abstract

The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes{<=}1000{angstrom}, and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1050 C to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors. 8 figs.

Inventors:
Publication Date:
Research Org.:
University of California
OSTI Identifier:
170453
Patent Number(s):
US 5,476,878/A/
Application Number:
PAN: 8-307,219
Assignee:
Univ. of California, Oakland, CA (United States) PTO; SCA: 360601; 250903; 250400; PA: EDB-96:028246; SN: 96001517614
DOE Contract Number:  
W-7405-ENG-48
Resource Type:
Patent
Resource Relation:
Other Information: PBD: 19 Dec 1995
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE; PHENOLS; POLYMERIZATION; FURFURAL; FOAMS; PRODUCTION; USES; CAPACITIVE ENERGY STORAGE EQUIPMENT; ELECTRODES; ELECTRIC BATTERIES; SOL-GEL PROCESS; PORE STRUCTURE; PYROLYSIS; FILTERS; PACKINGS; ION EXCHANGE MATERIALS

Citation Formats

Pekala, R.W. Organic aerogels from the sol-gel polymerization of phenolic-furfural mixtures. United States: N. p., 1995. Web.
Pekala, R.W. Organic aerogels from the sol-gel polymerization of phenolic-furfural mixtures. United States.
Pekala, R.W. Tue . "Organic aerogels from the sol-gel polymerization of phenolic-furfural mixtures". United States. doi:.
@article{osti_170453,
title = {Organic aerogels from the sol-gel polymerization of phenolic-furfural mixtures},
author = {Pekala, R.W.},
abstractNote = {The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes{<=}1000{angstrom}, and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1050 C to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors. 8 figs.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 19 00:00:00 EST 1995},
month = {Tue Dec 19 00:00:00 EST 1995}
}