Materials Data on RhN5Cl3 by Materials Project
RhN4ClNCl2 crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of four dichloramine molecules and four RhN4Cl ribbons oriented in the (1, 0, 0) direction. In each RhN4Cl ribbon, Rh4+ is bonded in a tetrahedral geometry to four N+0.20- atoms. There is two shorter (1.72 Å) and two longer (1.97 Å) Rh–N bond length. There are three inequivalent N+0.20- sites. In the first N+0.20- site, N+0.20- is bonded in a distorted bent 120 degrees geometry to one Rh4+ and one Cl1- atom. The N–Cl bond length is 1.59 Å. In the second N+0.20- site, N+0.20- is bonded in a single-bond geometry to one Rh4+ atom. In the third N+0.20- site, N+0.20- is bonded in a single-bond geometry to one Rh4+ atom. Cl1- is bonded in a bent 120 degrees geometry to two equivalent N+0.20- atoms.
- Research Organization:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Contributing Organization:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231
- OSTI ID:
- 1704462
- Report Number(s):
- mp-1179758
- Country of Publication:
- United States
- Language:
- English
Similar Records
Materials Data on RuN5Cl3 by Materials Project
Materials Data on RhN5Cl3 by Materials Project
Materials Data on IrN5Cl3 by Materials Project
Dataset
·
Thu Sep 03 00:00:00 EDT 2020
·
OSTI ID:1759863
Materials Data on RhN5Cl3 by Materials Project
Dataset
·
Thu Apr 30 00:00:00 EDT 2020
·
OSTI ID:1654988
Materials Data on IrN5Cl3 by Materials Project
Dataset
·
Thu Apr 30 00:00:00 EDT 2020
·
OSTI ID:1677915