Materials Data on LiIO3 by Materials Project
LiIO3 crystallizes in the orthorhombic Cmcm space group. The structure is one-dimensional and consists of two LiIO3 ribbons oriented in the (0, 0, 1) direction. Li1+ is bonded in a 6-coordinate geometry to six O2- atoms. There are four shorter (2.09 Å) and two longer (2.39 Å) Li–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Li1+ and two equivalent I5+ atoms. Both O–I bond lengths are 2.12 Å. In the second O2- site, O2- is bonded in a distorted T-shaped geometry to two equivalent Li1+ and one I5+ atom. The O–I bond length is 1.84 Å. I5+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms.
- Research Organization:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Contributing Organization:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231
- OSTI ID:
- 1698455
- Report Number(s):
- mp-1180548
- Country of Publication:
- United States
- Language:
- English
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Materials Data on LiIO3 by Materials Project
Materials Data on LiIO3 by Materials Project