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Title: Interfacial water shuffling the intermediates of hydrogen oxidation and evolution reactions in aqueous media

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/D0EE01754J· OSTI ID:1690138

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1690138
Report Number(s):
BNL-220462-2020-JACI
Journal Information:
Energy & Environmental Science, Vol. 13, Issue 9
Country of Publication:
United States
Language:
English

References (56)

Work function, electronegativity, and electrochemical behaviour of metals journal September 1972
Modeling the Electrochemical Hydrogen Oxidation and Evolution Reactions on the Basis of Density Functional Theory Calculations journal October 2010
Interfacial effects on the catalysis of the hydrogen evolution, oxygen evolution and CO2-reduction reactions for (co-)electrolyzer development journal November 2016
Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy journal January 2015
Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy journal March 2016
Perspective—Towards Establishing Apparent Hydrogen Binding Energy as the Descriptor for Hydrogen Oxidation/Evolution Reactions journal January 2018
Explanation of Dramatic pH-Dependence of Hydrogen Binding on Noble Metal Electrode: Greatly Weakened Water Adsorption at High pH journal May 2018
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption journal February 2013
Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts journal May 2012
Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes journal March 2017
Water dissociation on well-defined platinum surfaces: The electrochemical perspective journal March 2013
Temperature dependent surface electrochemistry on Pt single crystals in alkaline electrolytes journal May 2002
Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts journal January 2019
Determining the Viability of Hydroxide-Mediated Bifunctional HER/HOR Mechanisms through Single-Crystal Voltammetry and Microkinetic Modeling journal January 2018
The Effect of Noncovalent Interactions on the HOR, ORR, and HER on Ru, Ir, and Ru0.50Ir0.50 Metal Surfaces in Alkaline Environments journal June 2012
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces journal December 2011
The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum journal August 2009
Exploiting dynamic water structure and structural sensitivity for nanoscale electrocatalyst design journal October 2019
Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media journal November 2017
Metal and Metal Oxide Interactions and Their Catalytic Consequences for Oxygen Reduction Reaction journal June 2017
Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces journal January 2013
Influence of the NaOH Concentration on the Hydrogen Electrode Reaction Kinetics of Ni and NiCu Electrodes journal March 2020
EQCM Study of Ru and RuO2 Surface Electrochemistry journal May 2007
EQCM Study on Dissolution of Ruthenium in Sulfuric Acid journal January 2008
Ruthenium redox equilibria: 3. Pourbaix diagrams for the systems Ru-H2O and Ru-Cl--H2O journal April 2016
Structural and Architectural Evaluation of Bimetallic Nanoparticles: A Case Study of Pt−Ru Core−Shell and Alloy Nanoparticles journal October 2009
X-ray absorption fine structure determination of pH-dependent U-bacterial cell wall interactions journal November 2002
Metal-oxygen multiple bond lengths: a statistical study journal November 1988
Partial Dissociation of Water on Ru(0001) journal January 2002
The structure of mixed H2O–OH monolayer films on Ru(0001) journal October 2008
Different Surface Chemistries of Water on Ru{0001}:  From Monomer Adsorption to Partially Dissociated Bilayers journal March 2003
Origin of Superior HOR/HER Activity of Bimetallic Pt-Ru Catalysts in Alkaline Media Identified via Ru@Pt Core-Shell Nanoparticles journal January 2018
Elucidating Hydrogen Oxidation/Evolution Kinetics in Base and Acid by Enhanced Activities at the Optimized Pt Shell Thickness on the Ru Core journal October 2015
Hydrogen oxidation reaction on modified platinum model electrodes in alkaline media journal December 2019
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode journal November 2004
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes journal January 2010
Tracking Electrical Fields at the Pt/H 2 O Interface during Hydrogen Catalysis journal August 2019
Potential-Dependent Reorientation of Water Molecules at an Electrode/Electrolyte Interface Studied by Surface-Enhanced Infrared Absorption Spectroscopy journal January 1996
Hydrogen oxidation reaction in alkaline media: Relationship between electrocatalysis and electrochemical double-layer structure journal November 2017
Surface science studies of model fuel cell electrocatalysts journal April 2002
Electrocatalysis by ad-atoms journal April 1975
Adsorbed Hydroxide Does Not Participate in the Volmer Step of Alkaline Hydrogen Electrocatalysis journal November 2017
Temperature-Dependent Surface Electrochemistry on Pt Single Crystals in Alkaline Electrolyte:  Part 1:  CO Oxidation journal November 2001
Trends in Selective Hydrogen Peroxide Production on Transition Metal Surfaces from First Principles journal November 2012
Correlation between CO Oxidation and H Adsorption/Desorption on Pt Surfaces in a Wide pH Range: The Role of Alkali Cations journal January 2017
Correcting the Hydrogen Diffusion Limitation in Rotating Disk Electrode Measurements of Hydrogen Evolution Reaction Kinetics journal January 2015
Kinetic Isotope Effects Quantify pH-Sensitive Water Dynamics at the Pt Electrode Interface journal March 2020
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism journal January 2014
pH and Alkali Cation Effects on the Pt Cyclic Voltammogram Explained Using Density Functional Theory journal December 2015
A model for electrochemical proton-transfer reactions journal March 1998
A basic solution journal March 2013
Lattice-confined Ru clusters with high CO tolerance and activity for the hydrogen oxidation reaction journal April 2020
Atomistic Explanation of the Dramatically Improved Oxygen Reduction Reaction of Jagged Platinum Nanowires, 50 Times Better than Pt journal April 2020
Water as a Promoter and Catalyst for Dioxygen Electrochemistry in Aqueous and Organic Media journal October 2015
Best Practices and Testing Protocols for Benchmarking ORR Activities of Fuel Cell Electrocatalysts Using Rotating Disk Electrode journal May 2017
Activity Descriptor Identification for Oxygen Reduction on Platinum-Based Bimetallic Nanoparticles: In Situ Observation of the Linear Composition–Strain–Activity Relationship journal January 2015

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