Methanol to aromatics: isolated zinc phosphate groups on HZSM-5 zeolite enhance BTX selectivity and catalytic stability

Qiao, Jian; Wang, Jianqiang; Frenkel, Anatoly I.; Teng, Jiawei; Chen, Xiqiang; Xiao, Jingxian; Zhang, Tiezhu; Wang, Zhendong; Yuan, Zhiqing; Yang, Weimin

doi:10.1039/c9ra09657d

Methanol to aromatics: isolated zinc phosphate groups on HZSM-5 zeolite enhance BTX selectivity and catalytic stability

Journal Article · Wed Feb 05 00:00:00 EST 2020 · RSC Advances

DOI:https://doi.org/10.1039/c9ra09657d· OSTI ID:1690002

^[1]; Wang, Jianqiang ^[1]; Frenkel, Anatoly I. ^[2]; Teng, Jiawei ^[1]; Chen, Xiqiang ^[1]; Xiao, Jingxian ^[1]; Zhang, Tiezhu ^[1]; Wang, Zhendong ^[1]; Yuan, Zhiqing ^[1]; Yang, Weimin ^[1]

Shanghai Research Institute of Petrochemical Technology (SINOPEC) (China)
Stony Brook Univ., NY (United States)

HZSM-5 zeolite combined with unique zinc and phosphorus species, yields excellent selectivity (~85%) to BTX (benzene, toluene, xylenes) in aromatic products. It was found that both zinc and phosphorus species were highly distributed in the pores of the zeolite channel network to form isolated zinc phosphate groups, which directly bond to the surface of zeolite, leading to a strong Lewis acidic center and an optimized surface acidity distribution favorable for BTX formation and the hydrothermal stability of the catalyst.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Key Research and Development Program of China; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-98CH10886; SC0012704

OSTI ID:: 1690002

Report Number(s):: BNL-220330-2020-JACI

Journal Information:: RSC Advances, Journal Name: RSC Advances Journal Issue: 10 Vol. 10; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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