skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Spectroscopic characterization of metal ligation in trinuclear iron-μ3-oxo-based complexes and metal-organic frameworks

Journal Article · · Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.5096796· OSTI ID:1688805

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1688805
Report Number(s):
BNL-220137-2020-JACI
Journal Information:
Journal of Chemical Physics, Vol. 150
Country of Publication:
United States
Language:
English

References (74)

Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials journal August 2013
Functional Hybrid Porous Coordination Polymers journal September 2013
Metal–Organic Frameworks as Platforms for Functional Materials journal February 2016
Metal-Organic Frameworks as Catalysts for Oxidation Reactions journal April 2016
Incorporation of Molecular Catalysts in Metal-Organic Frameworks for Highly Efficient Heterogeneous Catalysis journal March 2017
An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors journal January 2017
Emerging Multifunctional Metal-Organic Framework Materials journal July 2016
In situ spectroscopy studies of CO 2 adsorption in a dually functionalized microporous metal–organic framework journal January 2015
Molecular Hydrogen “Pairing” Interaction in a Metal Organic Framework System with Unsaturated Metal Centers (MOF-74) journal October 2010
Adsorbate Interactions in Metal Organic Frameworks Studied by Vibrational Spectroscopy journal May 2014
Mechanism of Preferential Adsorption of SO 2 into Two Microporous Paddle Wheel Frameworks M(bdc)(ted) 0.5 journal November 2013
CO Adsorption on a Mixed-Valence Ruthenium Metal–Organic Framework Studied by UHV-FTIR Spectroscopy and DFT Calculations journal March 2013
Monitoring the Activation of a Flexible Metal–Organic Framework Using Structurally Sensitive Spectroscopy Techniques journal September 2013
Understanding the Preferential Adsorption of CO 2 over N 2 in a Flexible Metal–Organic Framework journal August 2011
Frontispiece: The Interaction of Guest Molecules with Co-MOF-74: A Vis/NIR and Raman Approach journal June 2018
In Situ X-ray Absorption Spectroscopy Studies of Kinetic Interaction between Platinum(II) Ions and UiO-66 Series Metal–Organic Frameworks journal September 2014
Privileged Phosphine-Based Metal–Organic Frameworks for Broad-Scope Asymmetric Catalysis journal February 2014
Metal–Organic Frameworks Stabilize Mono(phosphine)–Metal Complexes for Broad-Scope Catalytic Reactions journal July 2016
Chemoselective single-site Earth-abundant metal catalysts at metal–organic framework nodes journal August 2016
Titanium(III)-Oxo Clusters in a Metal–Organic Framework Support Single-Site Co(II)-Hydride Catalysts for Arene Hydrogenation journal December 2017
Selective Catalytic Olefin Epoxidation with Mn II -Exchanged MOF-5 journal December 2017
Selective Dimerization of Propylene with Ni-MFU-4 l journal April 2017
Local Structure of Framework Cu(II) in HKUST-1 Metallorganic Framework:  Spectroscopic Characterization upon Activation and Interaction with Adsorbates journal March 2006
Local Structure of CPO-27-Ni Metallorganic Framework upon Dehydration and Coordination of NO journal August 2008
Synthesis, characterization and CO2 uptake of a chiral Co(ii) metal–organic framework containing a thiazolidine-based spacer journal January 2012
Response of CPO-27-Ni towards CO, N2 and C2H4 journal January 2009
Reversible Capture and Release of Cl 2 and Br 2 with a Redox-Active Metal–Organic Framework journal April 2017
Probing Framework-Restricted Metal Axial Ligation and Spin State Patterns in a Post-Synthetically Reduced Iron-Porphyrin-Based Metal–Organic Framework journal March 2016
Spectroscopic interrogations of isostructural metalloporphyrin-based metal-organic frameworks with strongly and weakly coordinating guest molecules journal June 2016
NO Disproportionation at a Mononuclear Site-Isolated Fe 2+ Center in Fe 2+ -MOF-5 journal June 2015
Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of the Nature of a Bound Ligand journal April 2011
Insights into the Geometric and Electronic Structure of Transition Metal Centers from Valence-to-Core X-ray Emission Spectroscopy journal September 2015
Chemical dependence of interatomic X-ray transition energies and intensities – a study of Mn Kβ″ and Kβ2,5 spectra journal March 1999
X-ray emission spectroscopy journal August 2009
HERFD-XAS and valence-to-core-XES: new tools to push the limits in research with hard X-rays? journal January 2014
Valence to Core X-ray Emission Spectroscopy journal May 2014
X-ray Emission Spectroscopy To Study Ligand Valence Orbitals in Mn Coordination Complexes journal September 2009
Direct Detection of Oxygen Ligation to the Mn4Ca Cluster of Photosystem II by X-ray Emission Spectroscopy journal December 2009
Manganese Kβ X-ray Emission Spectroscopy As a Probe of Metal–Ligand Interactions journal September 2011
Valence-to-Core X-Ray Emission Spectroscopy of Iron-Carbonyl Complexes: Implications for the Examination of Catalytic Intermediates journal October 2013
Probing Valence Orbital Composition with Iron Kβ X-ray Emission Spectroscopy journal July 2010
Cobalt Kβ valence-to-core X-ray emission spectroscopy: a study of low-spin octahedral cobalt( iii ) complexes journal January 2016
Study of Iron Dimers Reveals Angular Dependence of Valence-to-Core X-ray Emission Spectra journal September 2014
X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor journal November 2011
The role of X-ray spectroscopy in understanding the geometric and electronic structure of nitrogenase journal June 2015
Kβ Valence to Core X-ray Emission Studies of Cu(I) Binding Proteins with Mixed Methionine – Histidine Coordination. Relevance to the Reactivity of the M- and H-sites of Peptidylglycine Monooxygenase journal March 2016
The Cu-CHA deNO x Catalyst in Action: Temperature-Dependent NH 3 -Assisted Selective Catalytic Reduction Monitored by Operando XAS and XES journal September 2016
Interaction of NH 3 with Cu-SSZ-13 Catalyst: A Complementary FTIR, XANES, and XES Study journal April 2014
Chemical Sensitivity of Valence-to-Core X-ray Emission Spectroscopy Due to the Ligand and the Oxidation State: A Computational Study on Cu-SSZ-13 with Multiple H 2 O and NH 3 Adsorption journal November 2017
Selective Catalytic Reduction of NO Over Fe-ZSM-5: Mechanistic Insights by Operando HERFD-XANES and Valence-to-Core X-ray Emission Spectroscopy journal September 2014
Reactivity of Surface Species in Heterogeneous Catalysts Probed by In Situ X-ray Absorption Techniques journal February 2013
Metal-Organic Frameworks Based on Trigonal Prismatic Building Blocks and the New “acs” Topology journal May 2005
A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units journal September 2004
Applications of Porous Metal–Organic Framework MIL-100(M) (M = Cr, Fe, Sc, Al, V) journal November 2018
Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks journal March 2007
Assembly of Metal–Organic Frameworks (MOFs) Based on Indium-Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage journal April 2007
Facile synthesis of MIL-100(Fe) under HF-free conditions and its application in the acetalization of aldehydes with diols journal January 2015
Synthesis and catalytic properties of MIL-100(Fe), an iron( iii ) carboxylate with large pores journal January 2007
Metal-organic frameworks as efficient catalytic systems for the synthesis of 1,5-benzodiazepines from 1,2-phenylenediamine and ketones journal October 2017
Inside Cover: Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption (Angew. Chem. Int. Ed. 34/2010) journal June 2010
Infrared study of the influence of reducible iron(iii) metal sites on the adsorption of CO, CO2, propane, propene and propyne in the mesoporous metal–organic framework MIL-100 journal January 2011
Spin frustration and concealed asymmetry: structure and magnetic spectrum of [Fe3O(O2CPh)6(py)3]ClO4·py † journal January 2001
Dual-array valence emission spectrometer (DAVES): A new approach for hard x-ray photon-in photon-out spectroscopies
  • Finkelstein, K. D.; Pollock, C. J.; Lyndaker, A.
  • PROCEEDINGS OF THE 12TH INTERNATIONAL CONFERENCE ON SYNCHROTRON RADIATION INSTRUMENTATION – SRI2015, AIP Conference Proceedings https://doi.org/10.1063/1.4952832
conference January 2016
Software update: the ORCA program system, version 4.0: Software update journal July 2017
The ORCA program system: The ORCA program system journal June 2011
Mössbauer spectra of two extended series of basic iron(III) carboxylates [Fe3O(O2CR)6(H2O)6]A (A− = ClO4 −, NO3 −) journal June 2010
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy journal January 2005
Accurate Coulomb-fitting basis sets for H to Rn journal January 2006
Experimental and Computational X-ray Emission Spectroscopy as a Direct Probe of Protonation States in Oxo-Bridged Mn IV Dimers Relevant to Redox-Active Metalloproteins journal October 2013
Raman spectroscopic study of the interaction of metal ions with pyridine and maleimide — models for nucleic acids journal August 1993
An infrared and Raman spectroscopic study of some metal pyridine tetracyanonickelate complexes journal July 1973
Vibrational spectra of carboxylato complexes—III. Trinuclear ‘basic’ acetates and formates of chromium(III), iron(III) and other transition metals journal January 1981
Enhanced raman spectra of ethylene and propylene adsorbed on silver journal August 1980
A Multiplet Analysis of Fe K-Edge 1s → 3d Pre-Edge Features of Iron Complexes journal July 1997

Similar Records

Spectroscopic characterization of metal ligation in trinuclear iron-μ 3 -oxo-based complexes and metal-organic frameworks
Journal Article · Tue May 07 00:00:00 EDT 2019 · Journal of Chemical Physics · OSTI ID:1688805

Long-Lived Photoinduced Charge Separation in a Trinuclear Iron-μ 3 -oxo-based Metal–Organic Framework
Journal Article · Wed Jun 14 00:00:00 EDT 2017 · Journal of Physical Chemistry. C · OSTI ID:1688805

Probing Framework-Restricted Metal Axial Ligation and Spin State Patterns in a Post-Synthetically Reduced Iron-Porphyrin-Based Metal–Organic Framework
Journal Article · Thu Apr 07 00:00:00 EDT 2016 · Journal of Physical Chemistry Letters · OSTI ID:1688805

Related Subjects