Materials Data on Rb2PtC4(IN2)2 by Materials Project
Rb2PtC4(N2I)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Rb1+ is bonded in a 9-coordinate geometry to six N3- and three equivalent I1- atoms. There are a spread of Rb–N bond distances ranging from 3.17–3.61 Å. There are a spread of Rb–I bond distances ranging from 3.95–4.12 Å. Pt2- is bonded in an octahedral geometry to four C+3.50+ and two equivalent I1- atoms. All Pt–C bond lengths are 2.02 Å. Both Pt–I bond lengths are 2.73 Å. There are two inequivalent C+3.50+ sites. In the first C+3.50+ site, C+3.50+ is bonded in a linear geometry to one Pt2- and one N3- atom. The C–N bond length is 1.17 Å. In the second C+3.50+ site, C+3.50+ is bonded in a linear geometry to one Pt2- and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one C+3.50+ atom. In the second N3- site, N3- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one C+3.50+ atom. I1- is bonded in a 1-coordinate geometry to three equivalent Rb1+ and one Pt2- atom.
- Research Organization:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Contributing Organization:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231
- OSTI ID:
- 1687243
- Report Number(s):
- mp-1194184
- Country of Publication:
- United States
- Language:
- English
Similar Records
Materials Data on Cs2PtC4(IN2)2 by Materials Project
Materials Data on K2PtC4(IN2)2 by Materials Project
Materials Data on Rb2PtC4(N2Cl)2 by Materials Project
Dataset
·
Sun May 03 00:00:00 EDT 2020
·
OSTI ID:1679242
Materials Data on K2PtC4(IN2)2 by Materials Project
Dataset
·
Thu Jul 23 00:00:00 EDT 2020
·
OSTI ID:1275520
Materials Data on Rb2PtC4(N2Cl)2 by Materials Project
Dataset
·
Mon May 04 00:00:00 EDT 2020
·
OSTI ID:1714268