Materials Data on Ca3Ge3(RhO6)2 by Materials Project
Ca3Ge3(RhO6)2 crystallizes in the cubic Ia-3d space group. The structure is three-dimensional. Ca2+ is bonded in a distorted body-centered cubic geometry to eight equivalent O2- atoms. There are four shorter (2.41 Å) and four longer (2.53 Å) Ca–O bond lengths. Rh3+ is bonded to six equivalent O2- atoms to form RhO6 octahedra that share corners with six equivalent GeO4 tetrahedra. All Rh–O bond lengths are 2.08 Å. Ge4+ is bonded to four equivalent O2- atoms to form GeO4 tetrahedra that share corners with four equivalent RhO6 octahedra. The corner-sharing octahedral tilt angles are 51°. All Ge–O bond lengths are 1.79 Å. O2- is bonded in a 4-coordinate geometry to two equivalent Ca2+, one Rh3+, and one Ge4+ atom.
- Research Organization:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Contributing Organization:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231
- OSTI ID:
- 1685449
- Report Number(s):
- mp-1214274
- Country of Publication:
- United States
- Language:
- English
Similar Records
Materials Data on Ca3Ge3(BiO6)2 by Materials Project
Materials Data on Ca3Ge3(MoO6)2 by Materials Project
Materials Data on Ca3Ge3(WO6)2 by Materials Project
Dataset
·
Fri May 29 00:00:00 EDT 2020
·
OSTI ID:1320922
Materials Data on Ca3Ge3(MoO6)2 by Materials Project
Dataset
·
Thu Apr 30 00:00:00 EDT 2020
·
OSTI ID:1321020
Materials Data on Ca3Ge3(WO6)2 by Materials Project
Dataset
·
Wed Apr 29 00:00:00 EDT 2020
·
OSTI ID:1321021