Structure and good piezoelectric performance in the complex system of Pb[(Zn,Ni)Nb]O3–Pb[(In,Yb)Nb]O3–Pb(Zr,Hf,Ti)O3

Zhang, Jianbo; Liu, Hui; Sun, Shengdong; Liu, Ye; Gao, Botao; Deng, Shiqing; Fan, Longlong; Chen, Jun

doi:10.1063/5.0006390

Title: Structure and good piezoelectric performance in the complex system of Pb[(Zn,Ni)Nb]O₃–Pb[(In,Yb)Nb]O₃–Pb(Zr,Hf,Ti)O₃

Journal Article · Wed Jul 08 00:00:00 EDT 2020 · Journal of Applied Physics

DOI:https://doi.org/10.1063/5.0006390· OSTI ID:1681216

Zhang, Jianbo ^[1]; Liu, Hui ^[1]; Sun, Shengdong ^[1]; Liu, Ye ^[1]; Gao, Botao ^[1];

^[1]; Fan, Longlong ^[2];

^[1]

Univ. of Science and Technology, Beijing (China)
Tianjin Normal Univ. (China)

High-performance piezoelectrics are always demanded for the high-end application. In this study, a complex piezoelectric system of 0.49Pb(Zn_1/2Ni_1/2)_1/3Nb_2/3O₃–xPb(In_1/2Yb_1/2)_1/2Nb_1/2O₃–(0.51 –x)Pb(Zr_1/2Hf_1/2)_0.1Ti_0.9O₃ (0.16 ≤ x ≤ 0.23) was fabricated through the solid-state method. The structure, ferroelectric, piezoelectric, and dielectric properties were investigated. The optimum piezoelectric coefficient d₃₃ of 761 pC/N, high Curie temperature of 169 °C, dielectric permittivity (ε_r) of 4557, and electromechanical coupling coefficient (k_p) of 63% were found at the morphotropic phase boundary composition of x = 0.19, which are superior to other complex piezoelectric materials. In particular, a significant large-signal $d_{33}^{*}$ of 913 pm/V and low strain hysteresis (6%) was obtained in the temperature range of 20–170 °C. Temperature-dependent x-ray diffraction (XRD) has demonstrated that good temperature stability is put down to the structure stability. The agreement between the calculated lattice strain from in situ high-energy synchrotron XRD data and the macroscopic measurements suggests that the large lattice strain has a dominant contribution to the high piezoelectric response. The high piezoelectric performance and good temperature stability makes it potential for application.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC); National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities (China); Japan Synchrotron Radiation Research Inst. (JASRI)

Grant/Contract Number:: AC02-06CH11357; 21825102; 21701126; 21731001; FRF-TP-18-001C2; 2019A1167; 2019A1095; 2019A1340; 2019B1120

OSTI ID:: 1681216

Journal Information:: Journal of Applied Physics, Vol. 128, Issue 2; ISSN 0021-8979

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Structure and good piezoelectric performance in the complex system of Pb[(Zn,Ni)Nb]O3–Pb[(In,Yb)Nb]O3–Pb(Zr,Hf,Ti)O3

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Title: Structure and good piezoelectric performance in the complex system of Pb[(Zn,Ni)Nb]O₃–Pb[(In,Yb)Nb]O₃–Pb(Zr,Hf,Ti)O₃