Electrolyte Solvation and Ionic Association. VII. Correlating Raman Spectroscopic Data with Solvate Species
Journal Article
·
· Journal of the Electrochemical Society
Raman spectroscopy is a widely utilized method for determining information about the solvate species present in electrolyte solutions. Difficulties arise, however, when interpreting the Raman data in terms of correlating the spectroscopic vibrational bands with specific solvate species. Examples are provided to demonstrate how erroneous conclusions may be drawn with regard to the identity and population (distribution) of the solvent-separated ion pair (SSIP), contact ion pair (CIP) and aggregate (AGG) solvate species frequently mentioned in the scientific literature.
- Research Organization:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- DOE Contract Number:
- AC36-08GO28308
- OSTI ID:
- 1677475
- Report Number(s):
- NREL/JA-5900-78069; MainId:31978; UUID:4c567a22-0c58-4e0f-abf2-c4a0106c957a; MainAdminID:18673
- Journal Information:
- Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 11 Vol. 167
- Country of Publication:
- United States
- Language:
- English
Similar Records
Solvate Structures and Computational/Spectroscopic Characterization of LiPF6 Electrolytes
SISGR: Linking Ion Solvation and Lithium Battery Electrolyte Properties
Electrolyte Solvation and Ionic Association: Part IX. Structures and Raman Spectroscopic Characterization of LiFSI Solvates
Journal Article
·
Thu Apr 23 00:00:00 EDT 2015
· Journal of Physical Chemistry C, 119(16):8492-85
·
OSTI ID:1221467
SISGR: Linking Ion Solvation and Lithium Battery Electrolyte Properties
Technical Report
·
Sun Sep 30 00:00:00 EDT 2012
·
OSTI ID:1068557
Electrolyte Solvation and Ionic Association: Part IX. Structures and Raman Spectroscopic Characterization of LiFSI Solvates
Journal Article
·
Sun Nov 27 19:00:00 EST 2022
· Journal of the Electrochemical Society
·
OSTI ID:2419630