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Materials Data on Yb(BRh)4 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1677405· OSTI ID:1677405
Yb(RhB)4 crystallizes in the orthorhombic Ccce space group. The structure is three-dimensional. there are two inequivalent Yb sites. In the first Yb site, Yb is bonded in a 10-coordinate geometry to twelve Rh and twelve B atoms. There are a spread of Yb–Rh bond distances ranging from 2.90–3.24 Å. There are a spread of Yb–B bond distances ranging from 2.96–3.26 Å. In the second Yb site, Yb is bonded in a 12-coordinate geometry to twelve Rh and twelve B atoms. There are a spread of Yb–Rh bond distances ranging from 2.96–3.18 Å. There are a spread of Yb–B bond distances ranging from 2.97–3.14 Å. There are three inequivalent Rh sites. In the first Rh site, Rh is bonded in a 6-coordinate geometry to three Yb and five B atoms. There are a spread of Rh–B bond distances ranging from 2.16–2.28 Å. In the second Rh site, Rh is bonded in a 5-coordinate geometry to three Yb and five B atoms. There are a spread of Rh–B bond distances ranging from 2.16–2.26 Å. In the third Rh site, Rh is bonded in a 5-coordinate geometry to three equivalent Yb and five B atoms. There are a spread of Rh–B bond distances ranging from 2.16–2.27 Å. There are three inequivalent B sites. In the first B site, B is bonded in a 6-coordinate geometry to three Yb, five Rh, and one B atom. The B–B bond length is 1.79 Å. In the second B site, B is bonded in a 6-coordinate geometry to three equivalent Yb, five Rh, and one B atom. The B–B bond length is 1.78 Å. In the third B site, B is bonded in a 6-coordinate geometry to three Yb, five Rh, and one B atom.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1677405
Report Number(s):
mp-1197168
Country of Publication:
United States
Language:
English

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