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Materials Data on TlBi3F10 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1675487· OSTI ID:1675487
TlBi3F10 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Tl1+ is bonded in a distorted tetrahedral geometry to four equivalent F1- atoms. All Tl–F bond lengths are 2.88 Å. Bi3+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are four shorter (2.31 Å) and four longer (2.49 Å) Bi–F bond lengths. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent Bi3+ atoms. In the second F1- site, F1- is bonded to one Tl1+ and three equivalent Bi3+ atoms to form a mixture of edge and corner-sharing FTlBi3 tetrahedra.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1675487
Report Number(s):
mp-1208058
Country of Publication:
United States
Language:
English

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