Oxiranes are a class of cyclic ethers formed in abundance during low-temperature combustion of hydrocarbons and biofuels, either via chain-propagating steps that occur from unimolecular decomposition of β-hydroperoxyalkyl radicals (β-˙QOOH) or from reactions of HÒO with alkenes. The cis- and trans-isomers of 2,3-dimethyloxirane are intermediates of n-butane oxidation, and while rate coefficients for β-˙QOOH → 2,3-dimethyloxirane + OH are reported extensively, subsequent reaction mechanisms of the cyclic ethers are not. As a result, chemical kinetics mechanisms commonly adopt simplified chemistry to describe the consumption of 2,3-dimethyloxirane by convoluting several elementary reactions into a single step, which may introduce mechanism truncation error—uncertainty derived from missing or incomplete chemistry. The present research examines the isomerdependence of 2,3-dimethyloxirane reaction mechanisms in support of ongoing efforts to minimize mechanism truncation error. Reaction mechanisms are inferred via the detection of products from Cl-initiated oxidation of both cis-2,3-dimethyloxirane and trans-2,3-dimethyloxirane using multiplexed photoionization mass spectrometry (MPIMS). The experiments were conducted at 10 Torr and temperatures of 650 K and 800 K. To complement the experiments, the enthalpies of stationary points on the ˙R + O2 surfaces were computed at the ccCA-PS3 level of theory. In total, 28 barrier heights were computed on the 2,3-dimethyloxiranylperoxy surfaces. Two notable aspects are low-lying pathways that form resonance-stabilized ketohydroperoxide-type radicals caused by ˙QOOH ring-opening when the unpaired electron is localized adjacent to the ether group, and cis-trans isomerization of ˙R and ˙QOOH radicals, via inversion, which enable reaction pathways otherwise restricted by stereochemistry. Several species were identified in the MPIMS experiments from ring opening of 2,3-dimethyloxiranyl radicals. Neither of the two conjugate alkene isomers prototypical of ˙R + O2 reactions were detected. Products were also identified from decomposition of ketohydroperoxide-type radicals. The present work provides the first analysis of 2,3-dimethyloxirane oxidation chemistry and reveals that consumption pathways are complex and require the expansion of submechanisms in chemical kinetics mechanisms.
Doner, Anna C., et al. "Isomer-Dependent Reaction Mechanisms of Cyclic Ether Intermediates: <em>cis</em>-23-Dimethyloxirane and <em>trans</em>-23-Dimethyloxirane.." International Journal of Chemical Kinetics, vol. 53, no. 1, Oct. 2020. https://doi.org/10.1002/kin.21429
Doner, Anna C., Davis, Matthew M., Koritzke, Alanna L., Christianson, Matthew G., Turney, Justin M., Schaefer, Henry F., Sheps, Leonid, Osborn, David L., Taatjes, Craig A., & Rotavera, Brandon (2020). Isomer-Dependent Reaction Mechanisms of Cyclic Ether Intermediates: <em>cis</em>-23-Dimethyloxirane and <em>trans</em>-23-Dimethyloxirane.. International Journal of Chemical Kinetics, 53(1). https://doi.org/10.1002/kin.21429
Doner, Anna C., Davis, Matthew M., Koritzke, Alanna L., et al., "Isomer-Dependent Reaction Mechanisms of Cyclic Ether Intermediates: <em>cis</em>-23-Dimethyloxirane and <em>trans</em>-23-Dimethyloxirane.," International Journal of Chemical Kinetics 53, no. 1 (2020), https://doi.org/10.1002/kin.21429
@article{osti_1671812,
author = {Doner, Anna C. and Davis, Matthew M. and Koritzke, Alanna L. and Christianson, Matthew G. and Turney, Justin M. and Schaefer, Henry F. and Sheps, Leonid and Osborn, David L. and Taatjes, Craig A. and Rotavera, Brandon},
title = {Isomer-Dependent Reaction Mechanisms of Cyclic Ether Intermediates: <em>cis</em>-23-Dimethyloxirane and <em>trans</em>-23-Dimethyloxirane.},
annote = {Oxiranes are a class of cyclic ethers formed in abundance during low-temperature combustion of hydrocarbons and biofuels, either via chain-propagating steps that occur from unimolecular decomposition of β-hydroperoxyalkyl radicals (β-˙QOOH) or from reactions of HÒO with alkenes. The cis- and trans-isomers of 2,3-dimethyloxirane are intermediates of n-butane oxidation, and while rate coefficients for β-˙QOOH → 2,3-dimethyloxirane + OH are reported extensively, subsequent reaction mechanisms of the cyclic ethers are not. As a result, chemical kinetics mechanisms commonly adopt simplified chemistry to describe the consumption of 2,3-dimethyloxirane by convoluting several elementary reactions into a single step, which may introduce mechanism truncation error—uncertainty derived from missing or incomplete chemistry. The present research examines the isomerdependence of 2,3-dimethyloxirane reaction mechanisms in support of ongoing efforts to minimize mechanism truncation error. Reaction mechanisms are inferred via the detection of products from Cl-initiated oxidation of both cis-2,3-dimethyloxirane and trans-2,3-dimethyloxirane using multiplexed photoionization mass spectrometry (MPIMS). The experiments were conducted at 10 Torr and temperatures of 650 K and 800 K. To complement the experiments, the enthalpies of stationary points on the ˙R + O2 surfaces were computed at the ccCA-PS3 level of theory. In total, 28 barrier heights were computed on the 2,3-dimethyloxiranylperoxy surfaces. Two notable aspects are low-lying pathways that form resonance-stabilized ketohydroperoxide-type radicals caused by ˙QOOH ring-opening when the unpaired electron is localized adjacent to the ether group, and cis-trans isomerization of ˙R and ˙QOOH radicals, via inversion, which enable reaction pathways otherwise restricted by stereochemistry. Several species were identified in the MPIMS experiments from ring opening of 2,3-dimethyloxiranyl radicals. Neither of the two conjugate alkene isomers prototypical of ˙R + O2 reactions were detected. Products were also identified from decomposition of ketohydroperoxide-type radicals. The present work provides the first analysis of 2,3-dimethyloxirane oxidation chemistry and reveals that consumption pathways are complex and require the expansion of submechanisms in chemical kinetics mechanisms.},
doi = {10.1002/kin.21429},
url = {https://www.osti.gov/biblio/1671812},
journal = {International Journal of Chemical Kinetics},
issn = {ISSN 1097-4601},
number = {1},
volume = {53},
place = {United States},
publisher = {Wiley},
year = {2020},
month = {10}}
Sandia National Laboratories (SNL-CA), Livermore, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC04-94AL85000
OSTI ID:
1671812
Report Number(s):
SAND--2020--9546J; 690502
Journal Information:
International Journal of Chemical Kinetics, Journal Name: International Journal of Chemical Kinetics Journal Issue: 1 Vol. 53; ISSN 0538-8066; ISSN 1097-4601
Journal Article
·
Fri Sep 19 00:00:00 EDT 2014
· Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
·OSTI ID:1236002