1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes

Fostvedt, Jade I.; Grant, Lauren N.; Kriegel, Benjamin M.; Obenhuber, Andreas H.; Lohrey, Trevor D.; Bergman, Robert G.; Arnold, John

doi:10.1039/D0SC03489D

1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes

Journal Article · Wed Nov 04 00:00:00 UTC 2020 · Chemical Science

DOI:https://doi.org/10.1039/D0SC03489D· OSTI ID:1671349

^[1]; ^[1]; ^[1]; Obenhuber, Andreas H. ^[1]; ^[2]; ^[1]; ^[2]

Department of Chemistry, University of California, Berkeley, USA
Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division

Another slice of pi: the addition of a second π-donor ligand engenders 1,2-addition and [2 + 2] cycloaddition reactivity across Nb-imido and Nb-oxo bonds.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: National Institutes of Health (NIH); National Science Foundation (NSF); US Air Force Office of Scientific Research (AFOSR); USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1671349

Alternate ID(s):: OSTI ID: 1763681

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 42 Vol. 11; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and β-diketiminato ligands Tomson, Neil C.; Arnold, John; Bergman, Robert G. Dalton Transactions, Vol. 40, Issue 30 https://doi.org/10.1039/c1dt10202h	journal	January 2011
The structure and chemistry of tris(pentafluorophenyl)borane protected mononuclear nitridotitanium complexes Fuller, Anna-Marie; Hughes, David L.; Jones, Garth A. Dalton Transactions, Vol. 41, Issue 18 https://doi.org/10.1039/c2dt00056c	journal	January 2012
Carbon–fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: from stoichiometric to catalytic hydrodefluorination Gianetti, Thomas L.; Bergman, Robert G.; Arnold, John Chemical Science, Vol. 5, Issue 6 https://doi.org/10.1039/c4sc00006d	journal	January 2014
Si–H addition followed by C–H bond activation induced by a terminal thorium imido metallocene: a combined experimental and computational study Ren, Wenshan; Zhou, Enwei; Fang, Bo Chemical Science, Vol. 5, Issue 8 https://doi.org/10.1039/c4sc00576g	journal	January 2014
Mercury CSD 2.0 – new features for the visualization and investigation of crystal structures Macrae, Clare F.; Bruno, Ian J.; Chisholm, James A. Journal of Applied Crystallography, Vol. 41, Issue 2 https://doi.org/10.1107/S0021889807067908	journal	March 2008
ORTEP -3 for Windows - a version of ORTEP -III with a Graphical User Interface (GUI) Farrugia, L. J. Journal of Applied Crystallography, Vol. 30, Issue 5 https://doi.org/10.1107/S0021889897003117	journal	October 1997
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Structure validation in chemical crystallography Spek, Anthony L. Acta Crystallographica Section D Biological Crystallography, Vol. 65, Issue 2, p. 148-155 https://doi.org/10.1107/S090744490804362X	journal	January 2009
Oxo and Imido Complexes of Rhenium and Molybdenum in Catalytic Reductions Du, Guodong; Abu-Omar, Mahdi Current Organic Chemistry, Vol. 12, Issue 14 https://doi.org/10.2174/138527208785740238	journal	September 2008

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