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Title: Palladium bis-pincer complexes with controlled rigidity and inter-metal distance

Journal Article · · Inorganic Chemistry Frontiers (Online)
DOI:https://doi.org/10.1039/D0QI01111H· OSTI ID:1670809

We report a series of redox-active bis(pincer) Pd( ii ) complexes in which the redox active units are based on either a diarylamido or a carbazolide framework.

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1670809
Journal Information:
Inorganic Chemistry Frontiers (Online), Journal Name: Inorganic Chemistry Frontiers (Online) Vol. 7 Journal Issue: 22; ISSN 2052-1553
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (57)

Transition Metal Catalyzed Synthesis of Arylamines and Aryl Ethers from Aryl Halides and Triflates: Scope and Mechanism journal August 1998
N,N ,N′,N′ - Tetraphenyl-1,4-phenylenediamine−Fluorene Alternating Conjugated Polymer: Synthesis, Characterization, and Electrochromic Application journal March 2010
Recent advances in triphenylamine-based electrochromic derivatives and polymers journal January 2018
N−C Cleavage in Pincer PNP Complexes of Palladium journal September 2004
Thermodynamics of Pyridine Coordination in 1,4-Phenylene Bridged Bimetallic (Pd, Pt) Complexes Containing Two N , C , N ‘ Motifs, 1,4-M 2 -[C 6 (CH 2 NR 2 ) 4 -2,3,5,6] journal December 2006
Untersuchungen zum anodischen Verhalten von Carbazolen und Indolo[3,2-b]carbazolen in Acetonitril journal January 1975
Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals journal January 1985
Hetero Cu(III)–Pd(II) Complex of a Dibenzo[ g , p ]chrysene-Fused Bis-dicarbacorrole with Stable Organic Radical Character journal October 2017
Polyindolo[3,2- b ]carbazoles:  A New Class of p-Channel Semiconductor Polymers for Organic Thin-Film Transistors journal September 2006
N−H Cleavage as a Route to Palladium Complexes of a New PNP Pincer Ligand journal February 2004
Ligand Reactivity in Diarylamido/Bis(Phosphine) PNP Complexes of Mn(CO) 3 and Re(CO) 3 journal October 2009
Carbon−Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides journal December 1998
Synthesis, Structures, and Properties of 1,2,4,5-Benzenetetrathiolate Linked Group 10 Metal Complexes journal November 2009
Understanding the Effect of Metal Centers on Charge Transport and Delocalization in Conducting Metallopolymers journal January 2017
A cautionary warning on the use of electrochemical measurements to calculate comproportionation constants for mixed-valence compounds journal January 2004
Metallopolymers with emerging applications journal April 2008
Magnitudes of Electron-Withdrawing Effects of the Trifluoromethyl Ligand in Organometallic Complexes of Copper and Nickel journal March 2010
Binuclear Palladium Complexes Supported by Bridged Pincer Ligands journal December 2011
Efficient Inorganic–Organic Hybrid Perovskite Solar Cells Based on Pyrene Arylamine Derivatives as Hole-Transporting Materials journal December 2013
Extraordinary Redox Activities in Ladder-Type Conjugated Molecules Enabled by B ← N Coordination-Promoted Delocalization and Hyperconjugation journal December 2018
Organic host materials for phosphorescent organic light-emitting diodes journal January 2011
Distance Dependence of Electron Transfer Rates journal May 1985
Conducting metallopolymers: the roles of molecular architecture and redox matching journal January 2005
Synthesis and electronic properties of a pentafluoroethyl-derivatized nickel pincer complex journal January 2012
Dinuclear Quinonoid-Bridged d 8 Metal Complexes with Redox-Active Azobenzene Stoppers: Electrochemical Properties and Electrochromic Behavior journal April 2014
Tetradentate selenium ligand as a building block for homodinuclear complexes of Pd(ii) and Ru(ii) having seven membered rings or bis-pincer coordination mode: high catalytic activity of Pd-complexes for Heck reaction journal January 2010
Arylamine organic dyes for dye-sensitized solar cells journal January 2013
Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions journal January 2012
Janus POCOP Pincer Complexes of Nickel journal October 2018
Comparison of the Electronic Properties of Diarylamido-Based PNZ Pincer Ligands: Redox Activity at the Ligand and Donor Ability Toward the Metal journal February 2015
Synthesis and Characterization of Pd Complexes of a Carbazolyl/Bis(Imine) NNN Pincer Ligand journal April 2011
Recent Trends in Metallopolymer Design: Redox-Controlled Surfaces, Porous Membranes, and Switchable Optical Materials Using Ferrocene-Containing Polymers journal May 2018
Mono- versus Dipalladation of the Durene-Based Tetrathioether Ligand 1,2,4,5-( t BuSCH 2 ) 4 C 6 H 2 . Structures of [PdCl(( t BuSCH 2 ) 4 C 6 H)] and [Pd 2 (( t BuSCH 2 ) 4 C 6 )(MeCN) 2 ][BF 4 ] 2 journal May 1998
The Localized-to-Delocalized Transition in Mixed-Valence Chemistry journal September 2001
Palladium-catalyzed amination of aryl halides and sulfonates journal March 1999
Frustrated Lewis pair-like splitting of aromatic C–H bonds and abstraction of halogen atoms by a cationic [( F PNP)Pt] + species journal January 2013
Tricarbonylrhenium(I) Complexes of Dinucleating Redox-Active Pincer Ligands journal February 2018
Structural, Spectroscopic, and Theoretical Elucidation of a Redox-Active Pincer-Type Ancillary Applied in Catalysis journal March 2008
The Class II/III Transition in Triarylamine Redox Systems journal September 1999
Charge-Transfer Transitions in Triarylamine Mixed-Valence Systems:  A Joint Density Functional Theory and Vibronic Coupling Study journal September 2002
Redox Communication between Two Diarylamido/Bis(phosphine) (PNP)M Moieties Bridged by Ynediyl Linkers (M = Ni, Pd, Pt) journal July 2020
Four-Electron Oxidative Formation of Aryl Diazenes Using a Tantalum Redox-Active Ligand Complex journal June 2008
Probing the redox non-innocence of dinuclear, three-coordinate Co(ii) nindigo complexes: not simply β-diketiminate variants journal January 2012
A Stable Aminyl Radical Metal Complex journal January 2005
The Stille Reaction, 38 Years Later journal March 2015
Intramolecularly Stabilized 1,4-Phenylene-Bridged Homo- and Heterodinuclear Palladium and Platinum Organometallic Complexes Containing N,C,N -Coordination Motifs; η 1 -SO 2 Coordination and Formation of an Organometallic Arenium Ion Complex with Two Pt−C σ-Bonds ¥ journal November 1998
A guideline for the arylation of positions 4 and 5 of thiazole via Pd-catalyzed cross-coupling reactions journal October 2010
1,4-Bis(diarylamino)-2,5-bis(4-cyanophenylethenyl)benzenes: Fluorophores Exhibiting Efficient Red and Near-Infrared Emissions in Solid State journal March 2012
Trends in Electron-Vibration and Electronic Interactions in Bis(dimethylamino) Mixed-Valence Systems: A Joint Experimental and Theoretical Investigation journal April 2008
Dimetallated thioether complexes as building blocks for organometallic coordination polymers and aggregates journal January 1993
Half-Wave Potential Splittings Δ E 1/2 as a Measure of Electronic Coupling in Mixed-Valent Systems: Triumphs and Defeats journal May 2014
EasySpin, a comprehensive software package for spectral simulation and analysis in EPR journal January 2006
Catalytic nitrene transfer by a zirconium( iv ) redox-active ligand complex journal January 2011
Designing Catalysts for Nitrene Transfer Using Early Transition Metals and Redox-Active Ligands journal October 2011
Preface: Forum on Redox-Active Ligands journal October 2011
Radical Ligands Confer Nobility on Base-Metal Catalysts journal February 2010
The stability of nitrogen-centered radicals journal January 2015