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Response of PETN detonators to elevated temperatures

Journal Article · · Proceedings of the Combustion Institute

In the present study, commercially available detonators with pentaerythritol tetranitrate (PETN) were subjected to elevated temperatures. The detonators were thermally ignited over a range of heating rates to measure ignition delay time and assess detonator violence. The violence of the detonator was quantified by measuring the velocity of the detonator closure disc (or “flyer”). The maximum flyer velocity of a thermally ignited detonator was comparable in magnitude to that obtained by initiating a room temperature pristine detonator with an exploding bridge wire (under the same confinement); however, the high flyer velocity was not an indication of deflagration to detonation transition (DDT) in the thermally ignited detonator. The detonator responded more violently than a thermally ignited detonator when initiated at 95% of the ignition delay time. Furthermore, inoperability thresholds were also measured by varying the detonator temperature and the threshold was found to be sensitive at detonator temperatures below the melting point of PETN.

Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC04-94AL85000; NA0003525
OSTI ID:
1670178
Alternate ID(s):
OSTI ID: 1777043
Report Number(s):
SAND--2020-5325J; 686249
Journal Information:
Proceedings of the Combustion Institute, Journal Name: Proceedings of the Combustion Institute Journal Issue: 3 Vol. 38; ISSN 1540-7489
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (7)

Thermal Decomposition of Pentaerythritol Tetranitrate journal August 2003
Transition from combustion to detonation in porous explosives journal July 1969
PETN Ignition Experiments and Models journal April 2010
Influence of the grain size of high explosives on the duration of a high conductivity zone at the detonation journal August 2019
814. The burning to detonation of solid explosives journal January 1960
Deflagration‐to‐detonation transition in granular pentaerythritol tetranitrate journal April 1996
Thermal conductivity of energetic materials journal October 2019

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