Revisiting the effects of molybdenum and tungsten alloying on corrosion behavior of nickel-chromium alloys in aqueous corrosion

Lutton Cwalina, K.; Demarest, C. R.; Gerard, A. Y.; Scully, J. R.

doi:10.1016/j.cossms.2019.03.002

Revisiting the effects of molybdenum and tungsten alloying on corrosion behavior of nickel-chromium alloys in aqueous corrosion

Journal Article · Tue Mar 26 00:00:00 EDT 2019 · Current Opinion in Solid State and Materials Science

DOI:https://doi.org/10.1016/j.cossms.2019.03.002· OSTI ID:1670004

Lutton Cwalina, K. ^[1]; Demarest, C. R. ^[2]; Gerard, A. Y. ^[2]; Scully, J. R. ^[2]

University of Virginia, Charlottesville, VA (United States); University of Virginia
University of Virginia, Charlottesville, VA (United States)

Minor alloying additions such as molybdenum (Mo) have major effects on the localized corrosion resistance of corrosion resistant alloys containing chromium. However, progress in alloy development is mostly based upon empirical observations, where any mechanistic insights are largely relegated to the latter stages of localized corrosion (i.e., stabilization and propagation) that are more readily accessible experimentally. For instance, it is well understood that Mo and tungsten (W) affect repassivation of local active, as well as widespread transpassive, corrosion sites and Mo surface enrichment during corrosion is well-documented. In this paper, a comprehensive examination of the functions and mechanism by which selected Mo and W operate to improve the passivity and resistance to breakdown during the initial stages of localized corrosion of the most common Ni-based solid solution alloys is presented. Furthermore, it is shown that Mo and W exert considerable influence on many stages of corrosion, including both passivation and film breakdown, re-enforcing old and introducing more recent ideas in this comprehensive review of the current state of corrosion research on Ni-Cr-(Mo + W) alloys.

View Accepted Manuscript (DOE)

Research Organization:: University of Virginia, Charlottesville, VA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016584

OSTI ID:: 1670004

Alternate ID(s):: OSTI ID: 1532777

Journal Information:: Current Opinion in Solid State and Materials Science, Journal Name: Current Opinion in Solid State and Materials Science Journal Issue: 3 Vol. 23; ISSN 1359-0286

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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