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Materials Data on Sn2SeS by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1667147· OSTI ID:1667147
Sn2SeS crystallizes in the orthorhombic Pmc2_1 space group. The structure is two-dimensional and consists of two Sn2SeS sheets oriented in the (0, 0, 1) direction. there are two inequivalent Sn2+ sites. In the first Sn2+ site, Sn2+ is bonded in a 3-coordinate geometry to one Se2- and two equivalent S2- atoms. The Sn–Se bond length is 2.80 Å. Both Sn–S bond lengths are 2.71 Å. In the second Sn2+ site, Sn2+ is bonded to four equivalent Se2- and one S2- atom to form a mixture of distorted edge and corner-sharing SnSe4S square pyramids. There are two shorter (2.81 Å) and two longer (3.32 Å) Sn–Se bond lengths. The Sn–S bond length is 2.66 Å. Se2- is bonded in a 3-coordinate geometry to five Sn2+ atoms. S2- is bonded in a trigonal non-coplanar geometry to three Sn2+ atoms.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1667147
Report Number(s):
mp-1218960
Country of Publication:
United States
Language:
English

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