Materials Data on NiH24C4S4N8(ClO4)2 by Materials Project
Ni(N2H4)2Cl2(CNH4SO2)4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four methanesulfonamide molecules and one Ni(N2H4)2Cl2 cluster. In the Ni(N2H4)2Cl2 cluster, Ni2+ is bonded in an octahedral geometry to four N2- and two equivalent Cl1- atoms. All Ni–N bond lengths are 2.20 Å. Both Ni–Cl bond lengths are 2.42 Å. There are two inequivalent N2- sites. In the first N2- site, N2- is bonded in a distorted water-like geometry to one Ni2+ and two H1+ atoms. There is one shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the second N2- site, N2- is bonded in a distorted water-like geometry to one Ni2+ and two H1+ atoms. There is one shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. There are four inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. Cl1- is bonded in a single-bond geometry to one Ni2+ atom.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1666801
- Report Number(s):
- mp-1205229
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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