Dressed Ion-Pair States of an Ultralong-Range Rydberg Molecule
Journal Article
·
· Physical Review Letters
We predict the existence of a universal class of ultralong-range Rydberg molecular states whose vibrational spectra form trimmed Rydberg series. A dressed ion-pair model captures the physical origin of these exotic molecules, accurately predicts their properties, and reveals features of ultralong-range Rydberg molecules and heavy Rydberg states with a surprisingly small Rydberg constant. The latter is determined by the small effective charge of the dressed anion, which outweighs the contribution of the molecule’s large reduced mass. This renders these molecules the only known few-body systems to have a Rydberg constant smaller than R∞/2.
- Research Organization:
- Purdue Univ., West Lafayette, IN (United States)
- Sponsoring Organization:
- USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
- Grant/Contract Number:
- SC0012193
- OSTI ID:
- 1661741
- Alternate ID(s):
- OSTI ID: 1670707
- Journal Information:
- Physical Review Letters, Journal Name: Physical Review Letters Vol. 125 Journal Issue: 12; ISSN 0031-9007
- Publisher:
- American Physical Society (APS)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
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