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Viable Materials with a Giant Magnetocaloric Effect

Journal Article · · Crystals
This review of the current state of magnetocalorics is focused on materials exhibiting a giant magnetocaloric response near room temperature. To be economically viable for industrial applications and mass production, materials should have desired useful properties at a reasonable cost and should be safe for humans and the environment during manufacturing, handling, operational use, and after disposal. The discovery of novel materials is followed by a gradual improvement of properties by compositional adjustment and thermal or mechanical treatment. Consequently, with time, good materials become inferior to the best. There are several known classes of inexpensive materials with a giant magnetocaloric effect, and the search continues. View Full-Text
Research Organization:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-07CH11358
OSTI ID:
1661582
Report Number(s):
IS-J--10-224
Journal Information:
Crystals, Journal Name: Crystals Journal Issue: 9 Vol. 10; ISSN 2073-4352
Publisher:
MDPICopyright Statement
Country of Publication:
United States
Language:
English

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Giant magnetocaloric effect in Ho 12 Co 7 compound journal January 2013
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Low-temperature reversible giant magnetocaloric effect in the HoCuAl compound journal October 2013
Giant magnetocaloric and magnetoresistance effects in ferrimagnetic Mn 1.9 Co 0.1 Sb alloy journal January 2014
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Material screening metrics and optimal performance of an active magnetic regenerator journal February 2017
Giant field-induced adiabatic temperature changes in In-based off-stoichiometric Heusler alloys journal April 2017
Magnetization, ESR, and giant magnetocaloric effects in nanocrystals of Haldane-chain compound Gd 2 BaNiO 5 journal September 2017
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Controlling magnetostructural transition and magnetocaloric effect in multi-component transition-metal-based materials journal May 2021
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Low temperature giant magnetocaloric effect in multiferroic GdMnO 3 single crystals journal March 2015
Giant magnetocaloric effect in Gd 2 NiMnO 6 and Gd 2 CoMnO 6 ferromagnetic insulators journal August 2015
Giant magnetocaloric effect near room temperature in the off-stoichiometric Mn–Co–Ge alloy journal November 2016
Tuning Martensitic Phase Transition by Non-Magnetic Atom Vacancy in MnCoGe Alloys and Related Giant Magnetocaloric Effect journal July 2016
A criterion for enhancing the giant magnetocaloric effect: (Ni–Mn–Ga)—a promising new system for magnetic refrigeration journal January 2004
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Great magnetic entropy change in La(Fe, M ) 13 ( M =Si, Al) with Co doping journal July 2000
Giant magnetocaloric effect in GdAlO 3 and a comparative study with GdMnO 3 journal December 2016
High-throughput search for caloric materials: the CaloriCool approach journal December 2017
Effects of the thermal and magnetic paths on first order martensite transition of disordered Ni 45 Mn 44 Sn 9 In 2 Heusler alloy exhibiting a giant magnetocaloric effect and magnetoresistance near room temperature journal April 2018
Martensitic transformation and giant magnetic entropy change in Ni 42.8 Mn 40.3 Co 5.7 Sn 11.2 alloy journal May 2014
Low field induced giant anisotropic magnetocaloric effect in DyFeO 3 single crystal journal February 2015
Observation of giant magnetocaloric effect under low magnetic fields in EuTi 1– x co x o 3 journal October 2017
Influences of La and Ce doping on giant magnetocaloric effect of EuTiO journal January 2018
Giant low-field magnetocaloric effect in EuTi 1 − x Nb x O 3 ( x = 0.05, 0.1, 0.15, and 0.2) compounds journal February 2020
Hints on the origin of the thermal hysteresis suppression in giant magnetocaloric thin films irradiatied with highly charged ions journal September 2015
Influence of fabrication conditions on giant magnetocaloric effect of Ni–Mn–Sn ribbons journal April 2013
Impact of cycle-hysteresis interactions on the performance of giant magnetocaloric effect refrigerants journal June 2016
Mastering hysteresis in magnetocaloric materials
  • Gutfleisch, O.; Gottschall, T.; Fries, M.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074 https://doi.org/10.1098/rsta.2015.0308
journal August 2016
Magnetic Moments and Unpaired Spin Densities in the Fe-Rh Alloys journal June 1964
Ubiquitous first-order transitions and site-selective vanishing of the magnetic moment in giant magnetocaloric MnFeSiP alloys detected by Mn 55 NMR journal September 2019
Influence of hydrogenation on the vibrational density of states of magnetocaloric LaFe 11.4 Si 1.6 H 1.6 journal February 2020
First-order magnetic phase transition in P r 2 In with negligible thermomagnetic hysteresis journal June 2020
Giant volume magnetostriction in the FeRh alloy journal August 1994
Magnetic phase transitions and the magnetothermal properties of gadolinium journal February 1998
Magnetocaloric effect and heat capacity in the phase-transition region journal January 1999
Nature of the first-order antiferromagnetic-ferromagnetic transition in the Ge-rich magnetocaloric compounds Gd 5 ( Si x Ge 1 − x ) 4 journal July 2000
Thermodynamics of the magnetocaloric effect journal September 2001
Itinerant-electron metamagnetic transition and large magnetocaloric effects in La ( Fe x Si 1 − x ) 13 compounds and their hydrides journal March 2003
Itinerant-electron metamagnetism and giant magnetocaloric effect journal November 2003
Calculation of the giant magnetocaloric effect in the MnFeP 0.45 As 0.55 compound journal September 2004
Magnetostructural transition and magnetocaloric effect in Ni 55 Mn 20 Ga 25 single crystals journal September 2005
Giant magnetocaloric effect in tetragonal HoNi 2 B 2 C journal November 2005
Combined giant inverse and normal magnetocaloric effect for room-temperature magnetic cooling journal October 2007
Landau-type parametrization of the equation of state of a ferromagnet journal May 2008
Giant anisotropy of magnetocaloric effect in TbMnO 3 single crystals journal May 2011
Anisotropic magnetic properties and giant magnetocaloric effect in antiferromagnetic R MnO 3 crystals ( R = Dy , Tb, Ho, and Yb) journal December 2011
Ultrasonic triggering of giant magnetocaloric effect in MnAs thin films journal July 2012
Anisotropic magnetic properties and giant magnetocaloric effect of single-crystal PrSi journal April 2014
First-principles calculation of the instability leading to giant inverse magnetocaloric effects journal May 2014
Stable atomic structure of NiTi austenite journal August 2014
Moment evolution across the ferromagnetic phase transition of giant magnetocaloric ( Mn , Fe ) 2 ( P , Si , B ) compounds journal January 2015
Structure and giant inverse magnetocaloric effect of epitaxial Ni-Co-Mn-Al films journal May 2015
Giant reversible rotating cryomagnetocaloric effect in KEr ( MoO 4 ) 2 induced by a crystal-field anisotropy journal July 2015
Electronic and magnetic properties of phosphorus across the first-order ferromagnetic transition of ( Mn , Fe ) 2 ( P , Si , B ) giant magnetocaloric materials journal December 2015
Comment on “Giant anisotropy of magnetocaloric effect in TbMn O 3 single crystals” journal October 2017
Giant reversible magnetocaloric effect in a multiferroic GdFeO 3 single crystal journal November 2017
FeRh ground state and martensitic transformation journal January 2018
Determining the vibrational entropy change in the giant magnetocaloric material LaFe 11.6 Si 1.4 by nuclear resonant inelastic x-ray scattering journal July 2018
Giant magnetocaloric effect in an exchange-frustrated GdCrTiO 5 antiferromagnet journal September 2018
Anisotropic magnetic properties and giant rotating magnetocaloric effect in double-perovskite T b 2 CoMn O 6 journal November 2018
Magnetocaloric effect of gadolinium in high magnetic fields journal April 2019
Giant Rotating Magnetocaloric Effect in the Region of Spin-Reorientation Transition in the NdCo 5 Single Crystal journal September 2010
Shape-Memory Transformations of NiTi: Minimum-Energy Pathways between Austenite, Martensites, and Kinetically Limited Intermediate States journal December 2014
Giant Magnetocaloric Effect in Gd5(Si2Ge2) journal June 1997
Direct Measurement of the “Giant” Adiabatic Temperature Change in Gd 5 Si 2 Ge 2 journal September 1999
Making and Breaking Covalent Bonds across the Magnetic Transition in the Giant Magnetocaloric Material Gd 5 ( Si 2 Ge 2 ) journal May 2000
Field and Temperature Induced Magnetic Transition in G d 5 S n 4 : A Giant Magnetocaloric Material journal March 2003
Massive Magnetic-Field-Induced Structural Transformation in G d 5 G e 4 and the Nature of the Giant Magnetocaloric Effect journal November 2003
Pressure-Induced Three-Dimensional Ferromagnetic Correlations in the Giant Magnetocaloric Compound G d 5 G e 4 journal November 2003
Pressure Enhancement of the Giant Magnetocaloric Effect in T b 5 S i 2 G e 2 journal September 2004
Giant reversible magnetocaloric effect in the pyrochlore Er 2 Mn 2 O 7 due to a cooperative two-sublattice ferromagnetic order journal November 2017
Modulating the phase transition temperature of giant magnetocaloric thin films by ion irradiation journal November 2017
Giant magnetocaloric effect driven by indirect exchange in magnetic multilayers journal November 2018
Structure and giant inverse magnetocaloric effect of epitaxial Ni-Co-Mn-Al films conference May 2015
Fe doping effect on EuTiO 3 : The magnetic properties and giant magnetocaloric effect journal February 2019
Giant magnetocaloric effect near the curie temperature in the Sm0.6Sr0.4MnO3 manganite journal April 2001
Caloric and multicaloric effects in oxygen ferroics and multiferroics journal March 2015
Effect of Isovalent Cation Substitution on the Thermal, Caloric, and Magnetocaloric Properties of the (La1 – yEuy)0.7Pb0.3MnO3 Manganites journal January 2019
Thermomagnetic history effects across the first order magneto-structural transition in the giant magnetocaloric Fe-Rh alloy journal July 2008
Magnetocaloric Materials journal August 2000
Giant magnetocaloric effect and soft-mode magneto-structural phase transition in MnAs journal January 2008
Giant Magnetocaloric Effect in Manganites journal January 2010
Electricity without Fuel journal September 2019
Negative Thermal Expansion in the Materials With Giant Magnetocaloric Effect journal September 2018
Role of Potassium Substitution in the Magnetic Properties and Magnetocaloric Effect in La0.8−xKxBa0.05Sr0.15MnO3 (0 ≤ x ≤ 0.20) journal May 2020
Magnetocaloric Effect, Magnetoresistance of Sc0.28Ti0.72Fe2, and Phase Diagrams of Sc0.28Ti0.72Fe2−xTx Alloys with T = Mn or Co journal May 2020
Tuneable Giant Magnetocaloric Effect in (Mn,Fe)2(P,Si) Materials by Co-B and Ni-B Co-Doping journal December 2016
Large Inverse Magnetocaloric Effects and Giant Magnetoresistance in Ni-Mn-Cr-Sn Heusler Alloys journal January 2017
Giant Magnetocaloric Effect at Room Temperature and Low-Field Change in Fe78-xCrxSi4Nb5B12Cu1 Amorphous Alloys journal August 2008
Magnetic Properties and Giant Magnetocaloric Effects on the NiMn0.9Sb0.1 Compound journal December 2010
Recent Developments in Magnetic Refrigeration journal July 1999
Giant Magnetocaloric Effect in the Region of Magnetic Phase Transition in Mn (As,Sb) Compounds journal June 2012
Tuning the Curie temperature and thermal hysteresis of giant magnetocaloric (MnFe) 2 PX (X = Ge and Si) compounds by the Ru substitution journal May 2014

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Depth Profile of the Phase Transition of the FeRh Alloy in FeRh/BaTiO3 preprint January 2021

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