A Robust, Scalable Platform for the Electrochemical Conversion of CO₂ to Formate: Identifying Pathways to Higher Energy Efficiencies

Journal Article · Mon May 11 00:00:00 EDT 2020 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.0c00860· OSTI ID:1659870

Chen, Yingying ^[1]; Vise, Ashlee ^[1]; Klein, W. Ellis ^[1]; Cetinbas, Firat C. ^[2]; Myers, Deborah J. ^[2]; Smith, Wilson A. ^[3]; Deutsch, Todd G. ^[1]; Neyerlin, K. C. ^[1]

---

1. National Renewable Energy Lab. (NREL), Golden, CO (United States)
2. Argonne National Lab. (ANL), Lemont, IL (United States)
3. National Renewable Energy Lab. (NREL), Golden, CO (United States); Univ. of Colorado, Boulder, CO (United States)

This work demonstrated a robust, scalable cell architecture for electroreduction of CO₂ (CO₂R). An up to 90% faradaic efficiency for the conversion of CO₂R to formate at 500 mA/cm² was realized at a 25 cm2 gas diffusion electrode (GDE) with a carbon-supported SnO₂ electrocatalyst. Furthermore, a 1.27 mm thick catholyte was used between the bipolar membrane and cathode GDE, which could be further reduced to tens of micrometers upon refinement. The deconvolution of the potential drop from each individual component/process guides the pathways to higher energy efficiencies of CO₂R at this platform. Significant changes in the agglomerate size and aspect ratio on the electrode before and after an 11 h test were revealed by nano-CT, suggesting reduced CO₂ accessibility from electrode degradation. The versatility of this CO₂R testing platform enables the ability to assess materials, components, and interactions at scales more in line with future devices.

• Research Organization: National Renewable Energy Laboratory (NREL), Golden, CO (United States)
• Sponsoring Organization: USDOE Office of Energy Efficiency and Renewable Energy (EERE)
• Grant/Contract Number: AC02-06CH11357; AC36-08GO28308
• OSTI ID: 1659870
• Report Number(s): NREL/JA-5900-76373; MainId:6939; UUID:d2954d8f-c167-ea11-9c31-ac162d87dfe5; MainAdminID:13539
• Journal Information: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 6 Vol. 5; ISSN 2380-8195
• Publisher: American Chemical Society (ACS)
• Country of Publication: United States
• Language: English

Related Subjects

30 DIRECT ENERGY CONVERSION
cell architecture
electrochemical conversion
electroreduction