Multi-modal surface analysis of porous films under operando conditions

Eads, Calley N.; Zhong, Jian-Qiang; Kim, Donghun; Akter, Nusnin; Chen, Zhihengyu; Norton, Angela M.; Lee, Veronica; Kelber, Jeffry A.; Tsapatsis, Michael; Boscoboinik, J. Anibal; Sadowski, Jerzy T.; Zahl, Percy; Tong, Xiao; Stacchiola, Dario J.; Head, Ashley R.; Tenney, Samuel A.

doi:10.1063/5.0006220

Title: Multi-modal surface analysis of porous films under operando conditions

Journal Article · Tue Aug 04 00:00:00 EDT 2020 · AIP Advances

DOI:https://doi.org/10.1063/5.0006220· OSTI ID:1659689

Eads, Calley N. ^[1];

^[1]; Kim, Donghun ^[2]; Akter, Nusnin ^[3]; Chen, Zhihengyu ^[3]; Norton, Angela M. ^[4]; Lee, Veronica ^[5];

^[5]; Tsapatsis, Michael ^[6];

^[1];

^[1]; Zahl, Percy ^[1]; Tong, Xiao ^[1];

^[1];

^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Univ. of Minnesota, Minneapolis, MN (United States); Chonnam National Univ., Gwangju (South Korea)
Stony Brook Univ., NY (United States)
Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI); Univ. of Delaware, Newark, DE (United States)
Univ. of North Texas, Denton, TX (United States)
Univ. of Minnesota, Minneapolis, MN (United States); Johns Hopkins Univ., Baltimore, MD (United States)

Practical catalysts with a porous framework, such as zeolites, host catalytic reactions at active sites engrained in the pores and channels of the scaffold. The mechanism of interaction at these active sites, defining catalyst performance, remains elusive, in large part, due to the lack of surface characterization methods available for thick films or powders. Here, we present thin film analogs of practical catalysts that allow for the implementation of surface characterization tools, including advanced microscopy and operando spectroscopy methodologies. Specifically, we investigated bilayer silica, MFI nanosheets, and UiO-66 thin films using a multi-modal approach addressing film growth, characterization, and gas adsorption aimed at understanding catalytic activity, reactivity, and selectivity properties, as defined by molecular-level changes in the reaction mechanism.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI); Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: SC0012704; SC0001004

OSTI ID:: 1659689

Alternate ID(s):: OSTI ID: 1644716

Report Number(s):: BNL-216347-2020-JAAM; TRN: US2203759

Journal Information:: AIP Advances, Vol. 10, Issue 8; ISSN 2158-3226

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 10 works

Citation information provided by
Web of Science

References (61)

Studying two-dimensional zeolites with the tools of surface science: MFI nanosheets on Au(111) Kestell, John D.; Zhong, Jian-Qiang; Shete, Meera Catalysis Today, Vol. 280 https://doi.org/10.1016/j.cattod.2016.07.015	journal	February 2017
Growth and Structure of Crystalline Silica Sheet on Ru(0001) Löffler, D.; Uhlrich, J. J.; Baron, M. Physical Review Letters, Vol. 105, Issue 14 https://doi.org/10.1103/physrevlett.105.146104	journal	September 2010
New advances in the use of infrared absorption spectroscopy for the characterization of heterogeneous catalytic reactions Zaera, Francisco Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/c3cs60374a	journal	January 2014
Hydroxylation of Metal-Supported Sheet-Like Silica Films Yang, B.; Emmez, E.; Kaden, W. E. The Journal of Physical Chemistry C, Vol. 117, Issue 16 https://doi.org/10.1021/jp401935u	journal	April 2013
Hierarchical Nanomanufacturing: From Shaped Zeolite Nanoparticles to High-Performance Separation Membranes Snyder, Mark A.; Tsapatsis, Michael Angewandte Chemie International Edition, Vol. 46, Issue 40, p. 7560-7573 https://doi.org/10.1002/anie.200604910	journal	October 2007
In Situ Microscopy and Spectroscopy Applied to Surfaces at Work Han, Hui-Ling; Melaet, Gérôme; Alayoglu, Selim ChemCatChem, Vol. 7, Issue 22 https://doi.org/10.1002/cctc.201500642	journal	October 2015
Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory Valenzano, Loredana; Civalleri, Bartolomeo; Chavan, Sachin Chemistry of Materials, Vol. 23, Issue 7, p. 1700-1718 https://doi.org/10.1021/cm1022882	journal	April 2011
Metal-Organic Frameworks: Opportunities for Catalysis Farrusseng, David; Aguado, Sonia; Pinel, Catherine Angewandte Chemie International Edition, Vol. 48, Issue 41 https://doi.org/10.1002/anie.200806063	journal	September 2009
Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets Jeon, Mi Young; Kim, Donghun; Kumar, Prashant Nature, Vol. 543, Issue 7647 https://doi.org/10.1038/nature21421	journal	March 2017
Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy Lamberti, Carlo; Zecchina, Adriano; Groppo, Elena Chemical Society Reviews, Vol. 39, Issue 12 https://doi.org/10.1039/c0cs00117a	journal	January 2010
Ultrathin silica films on Pd(111): Structure and adsorption properties Tissot, Héloïse; Weng, Xuefei; Schlexer, Philomena Surface Science, Vol. 678 https://doi.org/10.1016/j.susc.2018.02.016	journal	December 2018
An experimental adsorbent screening study for CO2 removal from N2 Harlick, Peter J. E.; Tezel, F. Handan Microporous and Mesoporous Materials, Vol. 76, Issue 1-3 https://doi.org/10.1016/j.micromeso.2004.07.035	journal	December 2004
Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends Yuan, Shuai; Qin, Jun-Sheng; Lollar, Christina T. ACS Central Science, Vol. 4, Issue 4 https://doi.org/10.1021/acscentsci.8b00073	journal	February 2018
Coking and deactivation of zeolites Guisnet, M.; Magnoux, P. Applied Catalysis, Vol. 54, Issue 1 https://doi.org/10.1016/s0166-9834(00)82350-7	journal	September 1989
High-Pressure Studies of CO Adsorption on Pd(111) by X-ray Photoelectron Spectroscopy and Sum-Frequency Generation Kaichev, Vasiliy V.; Prosvirin, Igor P.; Bukhtiyarov, Valerii I. The Journal of Physical Chemistry B, Vol. 107, Issue 15 https://doi.org/10.1021/JP021992T	journal	April 2003
Spectroscopic studies of surface–gas interactions and catalyst restructuring at ambient pressure: mind the gap! Rupprechter, Günther; Weilach, Christian Journal of Physics: Condensed Matter, Vol. 20, Issue 18 https://doi.org/10.1088/0953-8984/20/18/184019	journal	April 2008
Synthesis and Applications of Molecular Sieve Layers and Membranes ^† Bein, Thomas Chemistry of Materials, Vol. 8, Issue 8 https://doi.org/10.1021/CM960148A	journal	January 1996
Thin silica films on Ru(0001): monolayer, bilayer and three-dimensional networks of [SiO4] tetrahedra Yang, Bing; Kaden, William E.; Yu, Xin Physical Chemistry Chemical Physics, Vol. 14, Issue 32 https://doi.org/10.1039/c2cp41355h	journal	January 2012
Exploring Zeolite Chemistry with the Tools of Surface Science: Challenges, Opportunities, and Limitations Boscoboinik, J. Anibal; Shaikhutdinov, Shamil Catalysis Letters, Vol. 144, Issue 12 https://doi.org/10.1007/s10562-014-1369-3	journal	September 2014
Direct observation of the phase transition between the (7 × 7) and (1 × 1) structures of clean (111) silicon surfaces Osakabe, N.; Tanishiro, Y.; Yagi, K. Surface Science, Vol. 109, Issue 2 https://doi.org/10.1016/0039-6028(81)90493-3	journal	August 1981
Energy Level Shifts at the Silica/Ru(0001) Heterojunction Driven by Surface and Interface Dipoles Wang, Mengen; Zhong, Jian-Qiang; Kestell, John Topics in Catalysis, Vol. 60, Issue 6-7 https://doi.org/10.1007/s11244-016-0704-x	journal	September 2016
CO adsorption on Pd(100) studied by multimodal ambient pressure X-ray photoelectron and infrared reflection absorption spectroscopies Head, Ashley R.; Karslıoǧlu, Osman; Gerber, Timm Surface Science, Vol. 665 https://doi.org/10.1016/j.susc.2017.08.009	journal	November 2017
Evolution of acid and basic sites in UiO-66 and UiO-66-NH2 metal-organic frameworks: FTIR study by probe molecules Chakarova, Kristina; Strauss, Ina; Mihaylov, Mihail Microporous and Mesoporous Materials, Vol. 281 https://doi.org/10.1016/j.micromeso.2019.03.006	journal	June 2019
Delineating similarities and dissimilarities in the use of metal organic frameworks and zeolites as heterogeneous catalysts for organic reactions Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes; Corma, Avelino Dalton Transactions, Vol. 40, Issue 24 https://doi.org/10.1039/c1dt10354g	journal	January 2011
Absolute CO coverage: Direct comparison between the (111) and (110) faces of Ni, Pd, and Pt at 300 K Erley, W.; Wagner, H. The Journal of Chemical Physics, Vol. 72, Issue 3 https://doi.org/10.1063/1.439324	journal	February 1980
Catalysis by Metal Organic Frameworks: Perspective and Suggestions for Future Research Yang, Dong; Gates, Bruce C. ACS Catalysis, Vol. 9, Issue 3 https://doi.org/10.1021/acscatal.8b04515	journal	January 2019
Mind the gap! Spectroscopy of catalytically active phases Rupprechter, Günther; Weilach, Christian Nano Today, Vol. 2, Issue 4 https://doi.org/10.1016/s1748-0132(07)70114-7	journal	August 2007
Zeolite acid strength and reaction mechanisms in catalysis Haw, James F. Phys. Chem. Chem. Phys., Vol. 4, Issue 22 https://doi.org/10.1039/b206483a	journal	January 2002
Ultra-thin silicate films on metals Shaikhutdinov, Shamil; Freund, Hans-Joachim Journal of Physics: Condensed Matter, Vol. 27, Issue 44 https://doi.org/10.1088/0953-8984/27/44/443001	journal	October 2015
Photoelastic modulation-reflection absorption infrared spectroscopy of CO on Pd(111) Stacchiola, D.; Thompson, A. W.; Kaltchev, M. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 20, Issue 6 https://doi.org/10.1116/1.1517995	journal	January 2002
Formation and Evolution of Ultrathin Silica Polymorphs on Ru(0001) Studied with Combined in Situ , Real-Time Methods Klemm, Hagen W.; Prieto, Mauricio J.; Peschel, Gina The Journal of Physical Chemistry C, Vol. 123, Issue 13 https://doi.org/10.1021/acs.jpcc.8b08525	journal	October 2018
The chemisorption of carbon monoxide on palladium single crystal surfaces: IR spectroscopic evidence for localised site adsorption Bradshaw, A. M.; Hoffmann, F. M. Surface Science, Vol. 72, Issue 3 https://doi.org/10.1016/0039-6028(78)90367-9	journal	April 1978
Ultrathin Silica Films: The Atomic Structure of Two-Dimensional Crystals and Glasses Büchner, Christin; Lichtenstein, Leonid; Yu, Xin Chemistry - A European Journal, Vol. 20, Issue 30 https://doi.org/10.1002/chem.201402452	journal	July 2014
Catalytic Consequences of Spatial Constraints and Acid Site Location for Monomolecular Alkane Activation on Zeolites Gounder, Rajamani; Iglesia, Enrique Journal of the American Chemical Society, Vol. 131, Issue 5 https://doi.org/10.1021/ja808292c	journal	February 2009
IR spectroscopy in catalysis Ryczkowski, Janusz Catalysis Today, Vol. 68, Issue 4 https://doi.org/10.1016/s0920-5861(01)00334-0	journal	July 2001
para -Xylene Ultra-selective Zeolite MFI Membranes Fabricated from Nanosheet Monolayers at the Air-Water Interface Kim, Donghun; Jeon, Mi Young; Stottrup, Benjamin L. Angewandte Chemie International Edition, Vol. 57, Issue 2 https://doi.org/10.1002/anie.201708835	journal	December 2017
Growth and Characterization of Crystalline Silica Films on Pd(100) Altman, Eric I.; Götzen, Jan; Samudrala, Niveditha The Journal of Physical Chemistry C, Vol. 117, Issue 49 https://doi.org/10.1021/jp4101152	journal	November 2013
Synthesis of free-standing chabazite-type films Lee, Hyunjung; Dutta, Prabir K. Microporous and Mesoporous Materials, Vol. 38, Issue 2-3 https://doi.org/10.1016/s1387-1811(99)00289-9	journal	August 2000
On-Surface Synthesis of Highly Oriented Thin Metal–Organic Framework Films through Vapor-Assisted Conversion Virmani, Erika; Rotter, Julian M.; Mähringer, Andre Journal of the American Chemical Society, Vol. 140, Issue 14 https://doi.org/10.1021/jacs.7b08174	journal	March 2018
Removal of Heavy Metals from Mine Waters by Natural Zeolites Wingenfelder, Ulla; Hansen, Carsten; Furrer, Gerhard Environmental Science & Technology, Vol. 39, Issue 12 https://doi.org/10.1021/ES048482S	journal	June 2005
Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts Choi, Minkee; Na, Kyungsu; Kim, Jeongnam Nature, Vol. 461, Issue 7261, p. 246-249 https://doi.org/10.1038/nature08288	journal	September 2009
Challenges and opportunities in IR nanospectroscopy measurements of energy materials Gross, Elad Nano Research, Vol. 12, Issue 9 https://doi.org/10.1007/s12274-019-2402-z	journal	April 2019
Model Catalysts: Simulating the Complexities of Heterogeneous Catalysts Gao, Feng; Goodman, D. Wayne Annual Review of Physical Chemistry, Vol. 63, Issue 1 https://doi.org/10.1146/annurev-physchem-032511-143722	journal	May 2012
Ordered porous materials for emerging applications Davis, Mark E. Nature, Vol. 417, Issue 6891, p. 813-821 https://doi.org/10.1038/nature00785	journal	June 2002
Ordered macro-microporous metal-organic framework single crystals Shen, Kui; Zhang, Lei; Chen, Xiaodong Science, Vol. 359, Issue 6372 https://doi.org/10.1126/science.aao3403	journal	January 2018
Engineering Metal Organic Frameworks for Heterogeneous Catalysis Corma, A.; García, H.; Llabrés i Xamena, F. X. Chemical Reviews, Vol. 110, Issue 8, p. 4606-4655 https://doi.org/10.1021/cr9003924	journal	August 2010
Aluminum-Phosphate Binder Formation in Zeolites as Probed with X-ray Absorption Microscopy van der Bij, Hendrik E.; Cicmil, Dimitrije; Wang, Jian Journal of the American Chemical Society, Vol. 136, Issue 51 https://doi.org/10.1021/ja508545m	journal	December 2014
Redox-Mediated Reconstruction of Copper during Carbon Monoxide Oxidation Xu, Fang; Mudiyanselage, Kumudu; Baber, Ashleigh E. The Journal of Physical Chemistry C, Vol. 118, Issue 29 https://doi.org/10.1021/jp5050496	journal	July 2014
Ultrathin Silica Films on Metals: The Long and Winding Road to Understanding the Atomic Structure Shaikhutdinov, Shamil; Freund, Hans-Joachim Advanced Materials, Vol. 25, Issue 1 https://doi.org/10.1002/adma.201203426	journal	November 2012
Modeling Zeolites with Metal-Supported Two-Dimensional Aluminosilicate Films Boscoboinik, Jorge Anibal; Yu, Xin; Yang, Bing Angewandte Chemie International Edition, Vol. 51, Issue 24 https://doi.org/10.1002/anie.201201319	journal	April 2012
MOF thin films: existing and future applications Shekhah, O.; Liu, J.; Fischer, R. A. Chemical Society Reviews, Vol. 40, Issue 2 https://doi.org/10.1039/c0cs00147c	journal	January 2011
Metal ion exchange by natural and modified zeolites Ćurković, L.; Cerjan-Stefanović, Š.; Filipan, T. Water Research, Vol. 31, Issue 6 https://doi.org/10.1016/s0043-1354(96)00411-3	journal	June 1997
Synthesis and Stability of Tagged UiO-66 Zr-MOFs Kandiah, Mathivathani; Nilsen, Merete Hellner; Usseglio, Sandro Chemistry of Materials, Vol. 22, Issue 24 https://doi.org/10.1021/cm102601v	journal	December 2010
Stand-alone polarization-modulation infrared reflection absorption spectroscopy instrument optimized for the study of catalytic processes at elevated pressures Kestell, John D.; Mudiyanselage, Kumudu; Ye, Xinyi Review of Scientific Instruments, Vol. 88, Issue 10 https://doi.org/10.1063/1.5007024	journal	October 2017
Oxidation and Reduction under Cover: Chemistry at the Confined Space between Ultrathin Nanoporous Silicates and Ru(0001) Zhong, Jian-Qiang; Kestell, John; Waluyo, Iradwikanari The Journal of Physical Chemistry C, Vol. 120, Issue 15 https://doi.org/10.1021/acs.jpcc.6b02851	journal	April 2016
Molecular Studies of Model Surfaces of Metals from Single Crystals to Nanoparticles under Catalytic Reaction Conditions. Evolution from Prenatal and Postmortem Studies of Catalysts ^† Somorjai, Gabor A.; Aliaga, Cesar Langmuir, Vol. 26, Issue 21 https://doi.org/10.1021/la101884s	journal	November 2010
Heterogeneous Catalysis Schlögl, Robert Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201410738	journal	February 2015
Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry Palomino, Robert M.; Hamlyn, Rebecca; Liu, Zongyuan Journal of Electron Spectroscopy and Related Phenomena, Vol. 221 https://doi.org/10.1016/j.elspec.2017.04.006	journal	November 2017
Characterization of Undercoordinated Zr Defect Sites in UiO-66 with Vibrational Spectroscopy of Adsorbed CO Driscoll, Darren M.; Troya, Diego; Usov, Pavel M. The Journal of Physical Chemistry C, Vol. 122, Issue 26 https://doi.org/10.1021/acs.jpcc.8b03283	journal	May 2018
Towards a molecular understanding of shape selectivity Smit, Berend; Maesen, Theo L. M. Nature, Vol. 451, Issue 7179 https://doi.org/10.1038/nature06552	journal	February 2008
Zeolites as catalysts in oil refining Primo, Ana; Garcia, Hermenegildo Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/c3cs60394f	journal	January 2014

Similar Records

Tandem synthesis of tetrahydroquinolines and identification of the reaction network by operando NMR

Journal Article · Tue Apr 20 00:00:00 EDT 2021 · Catalysis Science and Technology · OSTI ID:1659689

Chen, Jingwen; Qi, Long; Zhang, Biying; +7 more

In operando studies of CO oxidation on epitaxial SrCoO_2.5+δ thin films

Journal Article · Thu Aug 29 00:00:00 EDT 2019 · APL Materials · OSTI ID:1659689

Folkman, Chad M.; Chang, Seo Hyoung; Jeen, Hyoungjeen; +6 more

Operando Synthesis of Macroporous Molybdenum Diselenide Films for Electrocatalysis of the Hydrogen-Evolution Reaction

Journal Article · Thu Jul 17 00:00:00 EDT 2014 · ACS Catalysis · OSTI ID:1659689

Saadi, Fadl H.; Carim, Azhar I.; Velazquez, Jesus M.; +4 more

Related Subjects

36 MATERIALS SCIENCE
Adsorption
Reaction mechanisms
Atomic force microscopy
Nanomaterials
Operando spectroscopy
Thin films
Catalysts and Catalysis
Zeolites
Surface science

Title: Multi-modal surface analysis of porous films under operando conditions

Citation Formats

References (61)

Similar Records

Related Subjects