Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Topaz, a Potential Volatile-Carrier in Cold Subduction Zone: Constraint from Synchrotron X-ray Diffraction and Raman Spectroscopy at High Temperature and High Pressure

Journal Article · · Minerals
DOI:https://doi.org/10.3390/min10090780· OSTI ID:1659305
 [1];  [2];  [3];  [1];  [1];  [4];  [5];  [6];  [6];  [7]
  1. Chinese Academy of Sciences (CAS), Guiyang (China); Univ. of Chinese Academy of Sciences, Beijing (China)
  2. Univ. of Hawaii at Manoa, Honolulu, HI (United States)
  3. Zhejiang Geological Prospecting Inst. of China Chemical Geology and Mine Bureau, Hangzhou (China)
  4. Chinese Academy of Sciences (CAS), Guiyang (China); Univ. of Chinese Academy of Sciences, Beijing (China); Guizhou Polytechnic of Construction, Guiyang (China)
  5. Chinese Academy of Sciences (CAS), Guiyang (China); Univ. of Chinese Academy of Sciences, Beijing (China); Bureau of Natural Resources and Planning of Yongzhou (China)
  6. Chinese Academy of Sciences (CAS), Guiyang (China)
  7. Univ. of Chinese Academy of Sciences, Beijing (China)
+ Show Author Affiliations
The equation of state and stability of topaz at high-pressure/high-temperature conditions have been investigated by in situ synchrotron X-ray diffraction (XRD) and Raman spectroscopy in this study. No phase transition occurs on topaz over the experimental pressure–temperature ($P-T$) range. The pressure–volume data were fitted by the third-order Birch–Murnaghan equation of state (EoS) with the zero-pressure unit–cell volume V0 = 343.86 (9) Å3, the zero-pressure bulk modulus K0 = 172 (3) GPa, and its pressure derivative K’0 = 1.3 (4), while the obtained K0 = 155 (2) GPa when fixed K’0 = 4. In the pressure range of 0–24.4 GPa, the vibration modes of in-plane bending OH-groups for topaz show non-linear changes with the increase in pressure, while the other vibration modes show linear changes. Moreover, the temperature–volume data were fitted by Fei’s thermal equation with the thermal expansion coefficient α300 = 1.9 (1) × 10–5 K–1 at 300 K. Finally, the $P-T$ stability of topaz was studied by a synchrotron-based single-crystal XRD at simultaneously high $P-T$ conditions up to ~10.9 GPa and 700 K, which shows that topaz may maintain a metastable state at depths above 370 km in the upper mantle along the coldest subducting slab geotherm. Thus, topaz may be a potential volatile-carrier in the cold subduction zone. It can carry hydrogen and fluorine elements into the deep upper mantle and further affect the geochemical behavior of the upper mantle.
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
Chinese Academy of Sciences (CAS); National Natural Science Foundation of China (NSFC)
OSTI ID:
1659305
Journal Information:
Minerals, Journal Name: Minerals Journal Issue: 9 Vol. 10; ISSN 2075-163X
Publisher:
MDPICopyright Statement
Country of Publication:
United States
Language:
ENGLISH

References (63)

Thermal Structure of Lithosphere in North China journal January 2002
The pressure and temperature stability limits of lawsonite: implications for H2O recycling in subduction zones journal January 1994
Elastic behaviour and structural evolution of topaz at high pressure journal March 2006
Hydroxyl in mantle olivine xenocrysts from the Udachnaya kimberlite pipe journal April 2006
Behavior of epidote at high pressure and high temperature: a powder diffraction study up to 10 GPa and 1,200 K journal January 2011
Elastic behavior and pressure-induced structure evolution of topaz up to 45 GPa journal April 2014
Thermal equation of state of natural tourmaline at high pressure and temperature journal January 2016
Compressional behavior of natural eclogitic zoisite by synchrotron X-ray single-crystal diffraction to 34 GPa journal October 2018
High temperature stability limit of phase egg, AlSiO 3 (OH) journal October 1999
The transport of water in subduction zones journal January 2016
Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction journal March 1988
On the regional variation of heat flow, geotherms, and lithospheric thickness journal March 1977
The stability and composition of phengitic muscovite and associated phases from 5.5 to 11 GPa: Implications for deeply subducted sediments journal November 1996
Effects of water transportation on subduction dynamics: Roles of viscosity and density reduction journal November 2016
The effect of fluorine on the stability of wadsleyite: Implications for the nature and depths of the transition zone in the Earth's mantle journal January 2018
Granite subduction: Arc subduction, tectonic erosion and sediment subduction journal June 2009
Subduction zone geochemistry journal July 2019
Water content in natural eclogite and implication for water transport into the deep upper mantle journal February 2006
Crystal structure, equation of state, and elasticity of hydrous aluminosilicate phase, topaz-OH (Al2SiO4(OH)2) at high pressures journal February 2016
Thermal thickness and evolution of Precambrian lithosphere: A global study journal August 2001
Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions journal January 1986
Possible presence of high-pressure ice in cold subducting slabs journal December 2000
Single crystal elasticity of natural topaz at high-temperatures journal January 2018
A simple external resistance heating diamond anvil cell and its application for synchrotron radiation x-ray diffraction journal May 2010
BX90: A new diamond anvil cell design for X-ray diffraction and optical measurements journal December 2012
Toward an internally consistent pressure scale journal May 2007
The COMPRES/GSECARS gas-loading system for diamond anvil cells at the Advanced Photon Source journal September 2008
High pressure single-crystal micro X-ray diffraction analysis with GSE_ADA/RSV software journal August 2013
Two-dimensional detector software: From real detector to idealised image or two-theta scan journal January 1996
Hydrostatic limits of 11 pressure transmitting media journal March 2009
Distribution, cycling and impact of water in the Earth's interior journal October 2017
Abundance and Partitioning of OH in a High-pressure Magmatic System: Megacrysts from the Monastery Kimberlite, South Africa journal July 2004
EXPGUI , a graphical user interface for GSAS journal April 2001
CIF applications. XIV. Reporting of Rietveld results using pdCIF: GSAS2CIF journal September 2003
Effective hydrostatic limits of pressure media for high-pressure crystallographic studies journal January 2007
Experimental studies of mineralogical assemblages of metasedimentary rocks at Earth's mantle transition zone conditions journal February 2007
Orogenic and Anorogenic Granitoids in the Altay Mountains of Xinjiang and Their Discrimination Criteria: Orogenic and Anorogenic Granitoids of Altay Mts. journal March 1989
X-ray single-crystal structure refinement of an OH-rich topaz from Sulu UHP terrane (Eastern China) Structural foundation of the correlation between cell parameters and fluorine content [X-ray single-crystal structure refinement of an OH-rich topaz from Sulu UHP terrane (Eastern China) Structural foundation of the correlation between cell parameters and fluorine content] journal November 2003
Synthesis, properties and stability of Al3Si2O7(OH)3 (phase Pi), a hydrous high - pressure phase in the system Al2O3 - SiO2 - H2O (ASH) [Synthesis, properties and stability of Al3Si2O7(OH)3 (phase Pi), a hydrous high - pressure phase in the system Al2O3 - SiO2 - H2O (ASH)] journal July 1993
Topaz granites in northern Kazakhstan journal July 2008
Relation between cathodoluminescence and trace-element distribution of magmatic topaz from the Ary-Bulak massif, Russia journal August 2016
The fingerprint of imperial topaz from Ouro Preto region (Minas Gerais state, Brazil) based on cathodoluminescence properties and composition journal February 2018
EosFit7c and a Fortran module (library) for equation of state calculations journal January 2014
Thermoelastic properties of beryl, topaz, diaspore, sanidine and periclase journal January 1993
Volume behavior of hydrous minerals at high pressure and temperature; II, Compressibilities of lawsonite, zoisite, clinozoisite, and epidote journal April 1996
Hydroxyl-rich topaz in high-pressure and ultrahigh-pressure kyanite quartzites, with retrograde woodhouseite, from the Sulu terrane, eastern China journal April 2002
Effects of fluorine content on the elastic behavior of topaz [Al 2 SiO 4 (F,OH) 2 ] journal February 2017
Stability of Al-bearing superhydrous phase B at the mantle transition zone and the uppermost lower mantle journal August 2018
High-pressure single-crystal structural analysis of AlSiO3OH phase egg journal December 2018
Stability of the hydrous phases of Al-rich phase D and Al-rich phase H in deep subducted oceanic crust journal January 2019
Elasticity of single-crystal periclase at high pressure and temperature: The effect of iron on the elasticity and seismic parameters of ferropericlase in the lower mantle journal February 2019
Stability, composition, and crystal structure of Fe-bearing Phase E in the transition zone journal November 2019
A Cr3+ luminescence study of natural topaz Al2SiO4(F,OH)2 up to 60 GPa journal November 2019
Single-crystal elasticity of iron-bearing phase E and seismic detection of water in Earth's upper mantle journal October 2019
Thermoelasticity of tremolite amphibole: Geophysical implications journal June 2020
Incorporation of Mg in phase Egg, AlSiO3OH: Toward a new polymorph of phase H, MgSiH2O4, a carrier of water in the deep mantle journal January 2020
Pressure dependence of the OH-stretching mode in F-rich natural topaz and topaz-OH journal January 2005
Pressure dependence of the hydrogen-bond geometry in topaz-OD from neutron powder diffraction journal January 2008
Equations of State journal January 2000
Effect of temperature and pressure on the crystal structure of topaz, Al2SiO4(OH,F)2 journal January 2003
Stability and Solid Solutions of Hydrous Alumino-Silicates in the Earth’s Mantle journal April 2020
Dehydration of δ-AlOOH in Earth’s Deep Lower Mantle journal April 2020
High Pressure Single Crystal Diffraction at PX^2 journal January 2017

Similar Records

Isosymmetric pressure-induced bonding increase changes compression behavior of clinopyroxenes across jadeite-aegirine solid solution in subduction zones
Journal Article · Tue Nov 22 19:00:00 EST 2016 · Journal of Geophysical Research. Solid Earth · OSTI ID:1355027
Implications of Sound Velocities of Natural Topaz on the Seismic L–Discontinuity
Journal Article · Sun Jan 09 19:00:00 EST 2022 · Geophysical Research Letters · OSTI ID:1963553

Related Subjects

36 MATERIALS SCIENCE
Raman spectroscopy
Synchrotron X-ray diffraction
high pressure
high temperature
topaz