Iminoguanidines: from anion recognition and separation to carbon capture

Custelcean, Radu

doi:10.1039/D0CC04332J

Iminoguanidines: from anion recognition and separation to carbon capture

Journal Article · Tue Jul 21 00:00:00 EDT 2020 · ChemComm

DOI:https://doi.org/10.1039/D0CC04332J· OSTI ID:1657956

^[1]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Iminoguanidines, first reported in 1898, have received renewed attention in the last 5 years due to their ability to recognize and separate anions from competitive aqueous environments. Iminoguanidines display high recognition abilities towards hydrophilic oxyanions (e.g., sulfate, chromate, carbonate) through strong and complementary hydrogen bonding from the guanidinium groups. Here, this feature article reviews the fundamental anion recognition chemistry of iminoguanidines, as well as real-world applications including sulfate removal from seawater and CO₂ capture for climate change mitigations.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1657956

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 71 Vol. 56; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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