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Facilitating hydrogen atom migration via a dense phase on palladium islands to a surrounding silver surface

Journal Article · · Proceedings of the National Academy of Sciences of the United States of America
 [1];  [2];  [3];  [4];  [1];  [5];  [3];  [2];  [4];  [6]
  1. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138,
  2. Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, CA 90095,, Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095,
  3. Department of Chemistry, Tufts University, Medford, MA 02155,
  4. John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138,
  5. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY 11973-5000
  6. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138,, John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138,
Significance

The energy efficiency of catalytic processes hinges on achieving high selectivity and activity; bimetallic catalysts have potential to increase both by exploiting different chemical properties of the components. Transport of intermediates between the two metals, for example, transport of hydrogen atoms for selective hydrogenation, is required to capitalize on this bifunctionality. A mechanism for the migration of hydrogen atoms to silver from palladium is demonstrated here. Dihydrogen first dissociates on palladium, then forms a dense hydrogen phase on the palladium island. The dense phase includes weakly bound hydrogen atoms that are nearly isoenergetic with hydrogen on silver, rendering migration nearly energy neutral. The efficiency for hydrogen migration across the palladium−silver is maximized for small ensembles of palladium atoms.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-05CH11231; SC0012573
OSTI ID:
1657616
Journal Information:
Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Issue: 37 Vol. 117; ISSN 0027-8424
Publisher:
Proceedings of the National Academy of SciencesCopyright Statement
Country of Publication:
United States
Language:
English

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