Micelle-based nanoreactors containing Ru-porphyrin for the epoxidation of terminal olefins in water

Lu, Jie; Liang, Linus; Weck, Marcus

doi:10.1016/j.molcata.2016.02.033

Micelle-based nanoreactors containing Ru-porphyrin for the epoxidation of terminal olefins in water

Journal Article · Tue Mar 01 23:00:00 EST 2016 · Journal of Molecular Catalysis A: Chemical

DOI:https://doi.org/10.1016/j.molcata.2016.02.033· OSTI ID:1657175

Lu, Jie ^[1]; Liang, Linus ^[2]; ^[2]

New York University, NY (United States); NYU
New York University, NY (United States)

This contribution introduces a strategy to use Ru(II)-porphyrin complexes as catalysts for the epoxidation of alkenes in water. The design is based on shell-crosslinked micelle-based nanoreactors with hydrophobic cores and hydrophilic shells as supports for the Ru(II) porphyrin complexes. Here, the supported complexes are efficient catalysts for oxidation reactions, specifically the selectively oxidation of alkenes to epoxides. The presented strategy is the first system that allows for running Ru-catalyzed epoxidation reactions in water

View Accepted Manuscript (DOE)

Research Organization:: Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-03ER15459

OSTI ID:: 1657175

Journal Information:: Journal of Molecular Catalysis A: Chemical, Journal Name: Journal of Molecular Catalysis A: Chemical Vol. 417; ISSN 1381-1169

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol Ballistreri, Francesco; Gangemi, Chiara; Pappalardo, Andrea International Journal of Molecular Sciences, Vol. 17, Issue 7 https://doi.org/10.3390/ijms17071112	journal	July 2016
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Chain and Step Growth Polymerizations of Cyclic Imino Ethers: From Poly(2-oxazoline)s to Poly(ester amide)s Kempe, Kristian Macromolecular Chemistry and Physics, Vol. 218, Issue 11 https://doi.org/10.1002/macp.201700021	journal	March 2017
Acyl guanidine functional poly(2‐oxazoline)s as reactive intermediates and stimuli‐responsive materials Van Guyse, Joachim F. R.; Xu, Xiaowen; Hoogenboom, Richard Journal of Polymer Science Part A: Polymer Chemistry, Vol. 57, Issue 24 https://doi.org/10.1002/pola.29542	journal	November 2019
Recent Progress in Application of Molybdenum-Based Catalysts for Epoxidation of Alkenes Shen, Yirui; Jiang, Pingping; Wai, Phyu Catalysts, Vol. 9, Issue 1 https://doi.org/10.3390/catal9010031	journal	January 2019

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