Shock initiation of the HMX-based explosive PBX 9012: Experiments, uncertainty analysis, and unreacted equation-of-state

Journal Article · Tue Jun 02 00:00:00 EDT 2020 · Journal of Applied Physics

DOI:https://doi.org/10.1063/1.5144686· OSTI ID:1650642

Burns, Malcolm John  ^[1]; Chiquete, Carlos  ^[1]

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1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

In this study, shock initiation experiments have been carried out on the polymer-bonded explosive PBX 9012 [nominally 90% octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazine (HMX), 10% vinylidene–hexafluoropropylene copolymer (Viton A) by weight] in order to provide calibration data for the explosive’s unreacted equation-of-state (EOS) and shock-to-detonation transition for reactive burn rate calibration. The input pressures covered the range of 1.86–4.43 GPa. This provided run-to-detonation depths ranging from $>22.3\mathrm{mm}$ for the lowest pressure shot to 4.91 mm at the highest pressure. The relative shock sensitivity of PBX 9012 is compared to other HMX-explosives in terms of the Pop-plot, showing that the studied explosive is more sensitive than other similar HMX-based counterparts (with notable exceptions). The uncertainty in the shock velocity determinations from the shock tracker measurements are also investigated, yielding new uncertainty measures in the generated Hugoniot data and run-to-detonation coordinates. Finally, the unreacted equation-of-state is determined using a linear $U_s$– $u_p$ Mie–Grüneisen relation and the Davis reactants EOS analytical form, the latter being more suited for reactive burn modeling.

• Research Organization: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
• Sponsoring Organization: USDOE National Nuclear Security Administration (NNSA)
• Grant/Contract Number: 89233218CNA000001
• OSTI ID: 1650642
• Report Number(s): LA-UR-20-20210; TRN: US2203128
• Journal Information: Journal of Applied Physics, Vol. 127, Issue 21; ISSN 0021-8979
• Publisher: American Institute of Physics (AIP)
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
materials
shock sensitivity
shock waves
chemically reactive flows
equations of state
detonation velocity
explosives