Hierarchical nanotwins in single-crystal-like nickel with high strength and corrosion resistance produced via a hybrid technique

Li, Qiang; Xue, Sichuang; Price, Patrick; Sun, Xing; Ding, Jie; Shang, Zhongxia; Fan, Zhe; Wang, Han; Zhang, Yifan; Chen, Youxing; Wang, Haiyan; Hattar, Khalid; Zhang, Xinghang

doi:10.1039/c9nr07472d

Hierarchical nanotwins in single-crystal-like nickel with high strength and corrosion resistance produced via a hybrid technique

Journal Article · Thu Dec 05 23:00:00 EST 2019 · Nanoscale

DOI:https://doi.org/10.1039/c9nr07472d· OSTI ID:1650167

^[1]; Xue, Sichuang ^[1]; Price, Patrick ^[2]; Sun, Xing ^[1]; ^[1]; Shang, Zhongxia ^[1]; ^[3]; Wang, Han ^[1]; ^[1]; Chen, Youxing ^[4]; ^[5]; ^[2]; ^[1]

Purdue Univ., West Lafayette, IN (United States). School of Materials Engineering
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Univ. of North Carolina, Charlotte, NC (United States). Dept. of Mechanical Engineering and Engineering Science
Purdue Univ., West Lafayette, IN (United States). School of Materials Engineering and School of Electrical and Computer Engineering

High-density growth nanotwins enable high-strength and good ductility in metallic materials. However, twinning propensity is greatly reduced in metals with high stacking fault energy. In this study, we adopted a hybrid technique coupled with template-directed heteroepitaxial growth method to fabricate single-crystal-like, nanotwinned (nt) Ni. The nt Ni primarily contains hierarchical twin structures that consist of coherent and incoherent twin boundary segments with few conventional grain boundaries. In situ compression studies show the nt Ni has a high flow strength of ~2 GPa and good deformability. Moreover, the nt Ni has superb corrosion behavior due to the unique twin structure in comparison to coarse grained and nanocrystalline counterparts. The hybrid technique opens the door for the fabrication of a wide variety of single-crystal-like nt metals with unique mechanical and chemical properties.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000; SC0016337; NA0003525

OSTI ID:: 1650167

Alternate ID(s):: OSTI ID: 1579977

Report Number(s):: SAND--2020-8423J; 689933

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 3 Vol. 12; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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