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Coating adhesion of a chromate-containing epoxy primer on Al2024-T3 surface processed by laser-interference

Journal Article · · International Journal of Adhesion and Adhesives
In this work, the coating adhesion test results are presented for a primer that was coated on laser-interference structured surfaces of as-received Al2024-T3 specimens, i.e., without employing any polishing, cleaning, or any other surface alteration techniques. All of the laser-interference processing was performed by splitting the primary beam of a Q-switched Nd:YAG pulsed nanosecond laser into two beams and focused them to the same spot. The specimens were spray painted with a chromate-containing epoxy primer, CA7233, compliant to MIL-PRF-23377 Type I Class C2 specification. The adhesion of primer on Al surface with different treatments was assessed using the ASTM D3359 X-cut and cross-hatch tests. It was found that the laser processed specimens meet the performance requirements in the coating adhesion specifications by having a higher or identical ranking for coating adhesion specimens than those prepared with current state-of-the-art chemical conversion or sulfuric acid anodizing. The rastering with either 4 mm/s or 6 mm/s with a laser fluence of 1.78 J/cm2 is recommended to attain acceptable coating adhesion, even higher than that with the anodizing surface treatment.These results indicate that laser-interference shows significant potential as a non-chemical surface preparation technique for these coatings.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1649511
Alternate ID(s):
OSTI ID: 1631192
Journal Information:
International Journal of Adhesion and Adhesives, Journal Name: International Journal of Adhesion and Adhesives Journal Issue: N/A Vol. 102; ISSN 0143-7496
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (14)

Environmentally friendly Zn–Al layered double hydroxide (LDH)-based sol–gel corrosion protection coatings on AA 2024-T3 journal June 2019
Anodic oxidation of aluminium in sulphuric acid containing aluminium sulphate or magnesium sulphate journal January 1983
Initial investigation into the effectiveness of CO2-laser treatment of aluminium for adhesive bonding journal October 1995
Periodical micro-nano-structuring of metallic surfaces by interfering laser beams journal March 2003
Formation of a cerium-based conversion coating on AA2024: relationship with the microstructure journal January 2004
Advanced design of periodical architectures in bulk metals by means of Laser Interference Metallurgy journal December 2007
Surface chemistry and composition-induced variation of laser interference-based surface treatment of Al alloys journal September 2019
Corrosion performance of polyurethane hybrid coatings with encapsulated inhibitor journal May 2019
Surface analytical characterisation of Nd:YAG-laser pre-treated Al Mg3 as a preparation for bonding journal July 2012
Effect of Roughness and Surface Topography on Adhesion of PVB to AA2024-T3 using the Blister Test journal December 2013
Nonlinear Least-Squares Using Microcomputer Data Analysis Programs: KaleidaGraph™ in the Physical Chemistry Teaching Laboratory journal September 2000
Resistance Of Solid Surfaces To Wetting By Water journal August 1936
Postsealing Changes in Porous Aluminum Oxide Films Obtained in Sulfuric Acid Solutions journal January 2000
Nucleation and Growth of a Chromate Conversion Coating on Aluminum Alloy AA 2024-T3 journal January 2001