Understanding Binder–Silicon Interactions during Slurry Processing

Burdette-Trofimov, Katie; Armstrong, Beth L.; Heroux, Luke; Doucet, Mathieu; Yang, Guang; Kidder, Michelle; Phillip, Nathan D.; Rogers, Alexander; Veith, Gabriel

doi:10.1021/acs.jpcc.0c03660

Understanding Binder–Silicon Interactions during Slurry Processing

Journal Article · Tue May 19 00:00:00 UTC 2020 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.0c03660· OSTI ID:1649398

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The conformation of poly(acrylic acid) (PAA) as a function of shear during slurry processing to construct silicon-based anodes is elucidated via rheology-coupled ultra-small-angle neutron scattering (rheo-USANS). Rheo-USANS shows that PAA with encapsulated silicon exists as discrete aggregates that do not interact with one another. As a result, a well-connected matrix of silicon and carbon black dispersed in PAA does not exist; thus, the electrode is inhomogeneous. Raman mapping and X-ray photoelectron spectroscopy were used to confirm the electrode heterogeneity and further understand the cycling properties. These results are correlated to silicon surface chemistry to provide a pathway to making better electrodes.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1649398

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 24 Vol. 124; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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